Citation: Duan Zhi-Qiang, Gao Xin-Bao, Li Tian-Peng, Yao Kai, Xie Xu-Ming. A facile route to the hierarchical assembly of Au nanoparticles on carbon nanotubes through Cu²⁺ coordination for surfaceenhanced Raman scattering[J]. Chinese Chemical Letters, ;2017, 28(3): 521-524. doi: 10.1016/j.cclet.2016.11.031 shu

A facile route to the hierarchical assembly of Au nanoparticles on carbon nanotubes through Cu²⁺ coordination for surfaceenhanced Raman scattering

Duan Zhi-Qiang ^a ,
Gao Xin-Bao ^a,, ,
Li Tian-Peng ^a ,
Yao Kai ^a,b ,
Xie Xu-Ming ^c,,

a.
Shijiazhuang Mechanical Engineering College, Shijiazhuang 050003, China
b.
Department of Graduate Management, Equipment Academy, Beijing 101416, China
c.
Key Laboratory of Advanced Materials (MOE), Department of Chemical Engineering, Tsinghua University, ; Beijing 100084, China

Corresponding author: Gao Xin-Bao, xinbao_gao@163.com Xie Xu-Ming, xxm-dce@mail.tsinghua.edu.cn
Received Date: 12 July 2016
Revised Date: 2 August 2016
Accepted Date: 29 August 2016
Available Online: 5 March 2016

Figures(6)

We report the hierarchical assembly of Au nanoparticles on carboxylized carbon nanotubes (c-CNTs) through Cu²⁺ coordination. This route is facile and green, and can easily control the loading density of Au nanoparticles. The c-CNTs matrix ensures uniform distribution of Au nanoparticles, which is particularly important for the enrichment of hot spots while preventing their serious agglomeration. Moreover, the cCNT matrix also contributes to the electromagnetic enhancement due to its surface plasmon resonance, and the chemical enhancement due to the adsorption of the target molecules. The resulting Au@c-CNT nanohybrids exhibit a remarkable synergy in SERS compared to neat Au nanoparticles.
- Au nanoparticles,
- Carbon nanotubes,
- Coordination,
- Hierarchical assembly,
- Surface-enhanced Raman scattering
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沈阳化工大学材料科学与工程学院沈阳 110142

A facile route to the hierarchical assembly of Au nanoparticles on carbon nanotubes through Cu2+ coordination for surfaceenhanced Raman scattering

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通讯作者: 陈斌, bchen63@163.com

A facile route to the hierarchical assembly of Au nanoparticles on carbon nanotubes through Cu²⁺ coordination for surfaceenhanced Raman scattering