Citation: Xu Shi-Chao, Zhu Shou-Ji, Bi Liang-Wu, Chen Yu-Xiang, Wang Jing, Lu Yan-Ju, Gu Yan, Zhao Zhen-Dong. Solvent and additive-free selective aerobic allylic hydroxylation of β-pinene catalyzed by metalloporphyrins[J]. Chinese Chemical Letters, ;2017, 28(3): 575-578. doi: 10.1016/j.cclet.2016.11.020 shu

Solvent and additive-free selective aerobic allylic hydroxylation of β-pinene catalyzed by metalloporphyrins

Xu Shi-Chao ^a,b,c,d,e,f ,
Zhu Shou-Ji ^a,b,c,d ,
Bi Liang-Wu ^a,b,c,d,e,f ,
Chen Yu-Xiang ^a,b,c,d,e ,
Wang Jing ^a,b,c,d ,
Lu Yan-Ju ^a,b,c,d,e ,
Gu Yan ^a,b,c,d ,
Zhao Zhen-Dong ^{a,b,c,d,e,f,,}

a.
Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China
b.
Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China
c.
National Engineering Lab. for Biomass Chemical Utilization, Nanjing 210042, China
d.
Key and Open Lab. on Forest Chemical Engineering, State Forestry Administration, Nanjing 210042, China
e.
Institute of Forestry New Technology, Chinese Academy of Forestry, Beijing, 100091, China
f.
2011 Collaborative Innovation Center of Jiangxi Typical Trees Cultivation and Utilization in Jiangxi Agricultural University, Nanchang, 330045, China

Corresponding author: Zhao Zhen-Dong, zdzhao@189.cn
Received Date: 10 October 2016
Revised Date: 7 November 2016
Accepted Date: 8 November 2016
Available Online: 18 March 2016

Figures(6)

Metallodeuteroporphyrins (MDPs) were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed.
- Turpentine transformation,
- β-Pinene,
- Metalloporphyrin,
- Biomimetic catalysis,
- Aerobic allylic hydroxylation
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