Citation: Ullah Fateh, Chen Hongzheng, Li Chang-Zhi. Organic functional materials based buffer layers for efficient perovskite solar cells[J]. Chinese Chemical Letters, ;2017, 28(3): 503-511. doi: 10.1016/j.cclet.2016.11.009 shu

Organic functional materials based buffer layers for efficient perovskite solar cells

MOE Key Laboratory of Macromolecular Synthesis and Functionalization, State Key Laboratory of Silicon Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Li Chang-Zhi, czli@zju.edu.cn
Received Date: 28 July 2016
Revised Date: 4 October 2016
Accepted Date: 13 October 2016
Available Online: 11 March 2016

Figures(7)

In this review, we highlight the recent development of organic π-functional materials as buffer layers in constructing efficient perovskite solar cells (PVSCs). By following a brief introduction on the PVSC development, device architecture and material design features, we exemplified the exciting progresses made in field by exploiting organic π-functional materials based hole and electron transport layers (HTLs and ETLs) to enable high-performance PVSCs.
- Perovskite solar cells,
- Organic functional material,
- Hole transport layer,
- Electron transport layer,
- Power conversion efficiency
1. [1]
  Tang C.W.. Two-layer organic photovoltaic cell[J]. Appl. Phys. Lett., 1986,48:183-185. doi: 10.1063/1.96937
2. [2]
  Yu G., Gao J., Hummelen J.C., Wudl F., Heeger A.J.. Polymer photovoltaic cells:enhanced efficiencies via a network of internal donor-acceptor heterojunctions[J]. Science, 1995,270:1789-1791. doi: 10.1126/science.270.5243.1789
3. [3]
  O'Regan B., Grätzel M.. A low-cost, high-efficiency solar cell based on dyesensitized colloidal TiO₂ films[J]. Nature, 1991,353:737-740. doi: 10.1038/353737a0
4. [4]
  Mathew S., Yella A., Gao P.. Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers[J]. Nat. Chem., 2014,6:242-247. doi: 10.1038/nchem.1861
5. [5]
  You J.B., Dou L.T., Yoshimura K.. A polymer tandem solar cell with 10.6% power conversion efficiency[J]. Nat. Commun., 2013,41446. doi: 10.1038/ncomms2411
6. [6]
  Zhao J.B., Li Y.K., Yang G.F.. Efficient organic solar cells processed from hydrocarbon solvents[J]. Nat. Energy, 2016,115027. doi: 10.1038/nenergy.2015.27
7. [7]
  Zhao W.C., Qian D.P., Zhang S.Q.. Fullerene-free polymer solar cells with over 11% efficiency and excellent thermal stability[J]. Adv. Mater., 2016,28:4734-4739. doi: 10.1002/adma.v28.23
8. [8]
  Kojima A., Teshima K., Shirai Y., Miyasaka T.. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J]. J. Am. Chem. Soc., 2009,131:6050-6051. doi: 10.1021/ja809598r
9. [9]
  Im J.H., Lee C.R., Lee J.W., Park S.W., Park N.G.. 6.5% efficient perovskite quantum-dot-sensitized solar cell[J]. Nanoscale, 2011,3:4088-4093. doi: 10.1039/c1nr10867k
10. [10]
  Kim H.S., Lee C.R., Im J.H.. Lead iodide perovskite sensitized all-solidstate submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J]. Sci. Rep., 2012,2591.
11. [11]
  Zhang J., Hua Y., Xu B.. The role of 3D molecular structural control in new hole transport materials outperforming spiro-OMeTAD in perovskite solar cells[J]. Adv. Energy Mater., 2016,61601062. doi: 10.1002/aenm.201601062
12. [12]
  Frost J.M., Walsh A.. What is moving in hybrid halide perovskite solar cells?[J]. Accounts Chem. Res., 2016,49:528-535. doi: 10.1021/acs.accounts.5b00431
13. [13]
  Lee M.M., Teuscher J., Miyasaka T., Murakami T.N., Snaith H.J.. Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J]. Science, 2012,338:643-647. doi: 10.1126/science.1228604
14. [14]
  Ball J.M., Lee M.M., Hey A., Snaith H.J.. Low-temperature processed mesosuperstructured to thin-film perovskite solar cells[J]. Energy Environ. Sci., 2013,6:1739-1743. doi: 10.1039/c3ee40810h
15. [15]
  Burschka J., Pellet N., Moon S.J.. Sequential deposition as a route to highperformance perovskite-sensitized solar cells[J]. Nature, 2013,499:316-319. doi: 10.1038/nature12340
16. [16]
  Liu M.Z., Johnston M.B., Snaith H.J.. Efficient planar heterojunction perovskite solar cells by vapour deposition[J]. Nature, 2013,501:395-398. doi: 10.1038/nature12509
17. [17]
  Jeon N.J., Lee H.G., Kim Y.C.. o-Methoxy substituents in spiro-OMeTAD for efficient inorganic-organic hybrid perovskite solar cells[J]. J. Am. Chem. Soc., 2014,136:7837-7840. doi: 10.1021/ja502824c
18. [18]
  Park N.G.. Perovskite solar cells:an emerging photovoltaic technology[J]. Mater. Today, 2015,18:65-72. doi: 10.1016/j.mattod.2014.07.007
19. [19]
  Zhou H.P., Chen Q., Li G.. Interface engineering of highly efficient perovskite solar cells[J]. Science, 2014,345:542-546. doi: 10.1126/science.1254050
20. [20]
  Yang W.S., Noh J.H., Jeon N.J.. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange[J]. Science, 2015,348:1234-1237. doi: 10.1126/science.aaa9272
21. [21]
  Kim H., Lim K.G., Lee T.W.. Planar heterojunction organometal halide perovskite solar cells:roles of interfacial layers[J]. Energy Environ. Sci., 2016,9:12-30. doi: 10.1039/C5EE02194D
22. [22]
  Li C.Z., Yip H.L., Jen A.K.Y.. Functional fullerenes for organic photovoltaics[J]. J. Mater. Chem., 2012,22:4161-4177. doi: 10.1039/c2jm15126j
23. [23]
  Yip H.L., Jen A.K.Y.. Recent advances in solution-processed interfacial materials for efficient and stable polymer solar cells[J]. Energy Environ. Sci., 2012,5:5994-6011. doi: 10.1039/c2ee02806a
24. [24]
  Chueh C.C., Li C.Z., Jen A.K.Y.. Recent progress and perspective in solutionprocessed interfacial materials for efficient and stable polymer and organometal perovskite solar cells[J]. Energy Environ. Sci., 2015,8:1160-1189. doi: 10.1039/C4EE03824J
25. [25]
  Dong Q.F., Fang Y.J., Shao Y.C.. Electron-hole diffusion lengths >175 μm in solution-grown CH₃NH₃PbI₃ single crystals[J]. Science, 2015,347:967-970. doi: 10.1126/science.aaa5760
26. [26]
  Hou J.H., Chen H.Y., Zhang S.Q., Li G., Yang Y.. Synthesis characterization, and photovoltaic properties of a low band gap polymer based on silolecontaining polythiophenes and 2, 1, 3-benzothiadiazole[J]. J. Am. Chem. Soc., 2008,130:16144-16145. doi: 10.1021/ja806687u
27. [27]
  Huang Z.T., Xue G.B., Wu J.K.. Electron transport in solution-grown TIPSpentacene single crystals:effects of gate dielectrics and polar impurities[J]. Chin. Chem. Lett., 2016. doi: 10.1016/j.cclet.2016.05.016(inpress)
28. [28]
  Huang Z.T., Fan C.C., Xue G.B.. Solution-grown aligned crystals of diketopyrrolopyrroles (DPP)-based small molecules:rough surfaces and relatively low charge mobility[J]. Chin. Chem. Lett., 2016,27:523-526. doi: 10.1016/j.cclet.2016.01.054
29. [29]
  Lin Q.Q., Armin A., Nagiri R.C.R., Burn P.L., Meredith P.. Electro-optics of perovskite solar cells[J]. Nat. Photonics, 2015,9:106-112.
30. [30]
  Liu T.H., Chen K., Hu Q., Zhu R., Gong Q.H.. Inverted perovskite solar cells:progresses and perspectives[J]. Adv. Energy Mater., 2016,61600457. doi: 10.1002/aenm.v6.17
31. [31]
  Blom P.W.M., Mihailetchi V.D., Koster L.J.A., Markov D.E.. Device physics of polymer:fullerene bulk heterojunction solar cells[J]. Adv. Mater., 2007,19:1551-1566. doi: 10.1002/(ISSN)1521-4095
32. [32]
  Braun S., Salaneck W.R., Fahlman M.. Energy-level alignment at organic/metal and organic/organic interfaces[J]. Adv. Mater., 2009,21:1450-1472. doi: 10.1002/adma.v21:14/15
33. [33]
  Potscavage Jr. W.J., Sharma A., Kippelen B.. Critical interfaces in organic solar cells and their influence on the open-circuit voltage[J]. Acc. Chem. Res., 2009,42:1758-1767. doi: 10.1021/ar900139v
34. [34]
  Ratcliff E.L., Zacher B., Armstrong N.R.. Selective interlayers and contacts in organic photovoltaic cells[J]. J. Phys. Chem. Lett., 2011,2:1337-1350. doi: 10.1021/jz2002259
35. [35]
  Huang C.Y., Fu W.F., Li C.Z.. Dopant-free hole-transporting material with a C_3h symmetrical truxene core for highly efficient perovskite solar cells[J]. J. Am. Chem. Soc., 2016,138:2528-2531. doi: 10.1021/jacs.6b00039
36. [36]
  Bi C., Wang Q., Shao Y.C.. Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells[J]. Nat. Commun., 2015,67747. doi: 10.1038/ncomms8747
37. [37]
  Werner A., Li F., Harada K.. n-Type doping of organic thin films using cationic dyes[J]. Adv. Funct. Mater., 2004,14:255-260. doi: 10.1002/(ISSN)1616-3028
38. [38]
  Shao Y.C., Fang Y.J., Li T.. Grain boundary dominated ion migration in polycrystalline organic-inorganic halide perovskite films[J]. Energy Environ. Sci., 2016,9:1752-1759. doi: 10.1039/C6EE00413J
39. [39]
  de Quilettes D.W., Vorpahl S.M., Stranks S.D.. Impact of microstructure on local carrier lifetime in perovskite solar cells[J]. Science, 2015,348:683-686. doi: 10.1126/science.aaa5333
40. [40]
  Kan B., Li M.M., Zhang Q.. A series of simple oligomer-like small molecules based on oligothiophenes for solution-processed solar cells with high efficiency[J]. J. Am. Chem. Soc., 2015,137:3886-3893. doi: 10.1021/jacs.5b00305
41. [41]
  Jeon N.J., Noh J.H., Yang W.S.. Compositional engineering of perovskite materials for high-performance solar cells[J]. Nature, 2015,517:476-480. doi: 10.1038/nature14133
42. [42]
  Ryu S., Noh J.H., Jeon N.J.. Voltage output of efficient perovskite solar cells with high open-circuit voltage and fill factor[J]. Energy Environ. Sci., 2014,7:2614-2618. doi: 10.1039/C4EE00762J
43. [43]
  Tong X., Lin F., Wu J., Wang Z.M.. High performance perovskite solar cells[J]. Adv. Sci., 2016,31500201. doi: 10.1002/advs.201500201
44. [44]
  Susrutha B., Giribabu L., Singh S.P.. Recent advances in flexible perovskite solar cells[J]. Chem. Commun., 2015,51:14696-14707. doi: 10.1039/C5CC03666F
45. [45]
  Liu D.Y., Kelly T.L.. Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J]. Nat. Photonics, 2014,8:133-138.
46. [46]
  Huang F.Z., Dkhissi Y., Huang W.C.. Gas-assisted preparation of lead iodide perovskite films consisting of a monolayer of single crystalline grains for high efficiency planar solar cells[J]. Nano Energy, 2014,10:10-18. doi: 10.1016/j.nanoen.2014.08.015
47. [47]
  Bi D., Tress W., Dar M.I.. Efficient luminescent solar cells based on tailored mixed-cation perovskites[J]. Sci. Adv., 2016,2e1501170. doi: 10.1126/sciadv.1501170
48. [48]
  Liu T.H., Chen K., Hu Q.. Fast-growing procedure for perovskite films in planar heterojunction perovskite solar cells[J]. Chin. Chem. Lett., 2015,26:1518-1521. doi: 10.1016/j.cclet.2015.09.022
49. [49]
  Saliba M., Matsui T., Seo J.Y.. Cesium-containing triple cation perovskite solar cells:improved stability, reproducibility and high efficiency[J]. Energy Environ. Sci., 2016,9:1989-1997. doi: 10.1039/C5EE03874J
50. [50]
  Mun J.W., Cho I., Lee D.. Acetylene-bridged D-A-D type small molecule comprising pyrene and diketopyrrolopyrrole for high efficiency organic solar cells[J]. Org. Electron., 2013,14:2341-2347. doi: 10.1016/j.orgel.2013.05.035
51. [51]
  Li H., Fu K., Hagfeldt A.. A simple 3, 4-ethylenedioxythiophene based hole-transporting material for perovskite solar cells[J]. Angew. Chem. Int. Ed., 2014,53:4085-4088. doi: 10.1002/anie.201310877
52. [52]
  Li H.R., Fu K.W., Boix P.P.. Hole-transporting small molecules based on thiophene cores for high efficiency perovskite solar cells[J]. ChemSusChem, 2014,7:3420-3425. doi: 10.1002/cssc.v7.12
53. [53]
  Do K., Choi H., Lim K.. Star-shaped hole transporting materials with a triazine unit for efficient perovskite solar cells[J]. Chem. Commun., 2014,50:10971-10974. doi: 10.1039/C4CC04550E
54. [54]
  Saliba M., Orlandi S., Matsui T.. A molecularly engineered holetransporting material for efficient perovskite solar cells[J]. Nat. Energy, 2016,115017. doi: 10.1038/nenergy.2015.17
55. [55]
  Wang Y.K., Yuan Z.C., Shi G.Z.. Dopant-free spiro-triphenylamine/fluorene as hole-transporting material for perovskite solar cells with enhanced efficiency and stability[J]. Adv. Funct. Mater., 2016,26:1375-1381. doi: 10.1002/adfm.v26.9
56. [56]
  Bi D.Q., Xu B., Gao P.. Facile synthesized organic hole transporting material for perovskite solar cell with efficiency of 19.8%[J]. Nano Energy, 2016,23:138-144. doi: 10.1016/j.nanoen.2016.03.020
57. [57]
  Molina-Ontoria A., Zimmermann I., Garcia-Benito I.. Benzotrithiophene-based hole-transporting materials for 18.2% perovskite solar cells[J]. Angew. Chem. Int. Ed., 2016,55:6270-6274. doi: 10.1002/anie.201511877
58. [58]
  Xu B., Bi D.Q., Hua Y.. A low-cost spiro[J]. Energy Environ. Sci., 2016,9:873-877. doi: 10.1039/C6EE00056H
59. [59]
  Malinauskas T., Saliba M., Matsui T.. Branched methoxydiphenylaminesubstituted fluorene derivatives as hole transporting materials for highperformance perovskite solar cells[J]. Energy Environ. Sci., 2016,9:1681-1686. doi: 10.1039/C5EE03911H
60. [60]
  Choi H., Paek S., Lim N.. Efficient perovskite solar cells with 13.63% efficiency based on planar triphenylamine hole conductors[J]. Chemistry, 2014,20:10894-10899. doi: 10.1002/chem.201403807
61. [61]
  Choi H., Park S., Paek S.. Efficient star-shaped hole transporting materials with diphenylethenyl side arms for an efficient perovskite solar cell[J]. J. Mater. Chem. A, 2014,2:19136-19140. doi: 10.1039/C4TA04179H
62. [62]
  Rakstys K., Abate A., Dar M.I.. Triazatruxene-based hole transporting materials for highly efficient perovskite solar cells[J]. J. Am. Chem. Soc., 2015,137:16172-16178. doi: 10.1021/jacs.5b11076
63. [63]
  Nishimura H., Ishida N., Shimazaki A.. Hole-transporting materials with a two-dimensionallyexpanded π-system around an azulenecoreforefficient perovskite solar cells[J]. J. Am. Chem. Soc., 2015,137:15656-15659. doi: 10.1021/jacs.5b11008
64. [64]
  Lv S.T., Han L.Y., Xiao J.Y.. Mesoscopic TiO₂/CH₃NH₃PbI₃ perovskite solar cells with new hole-transporting materials containing butadiene derivatives[J]. Chem. Commun., 2014,50:6931-6934. doi: 10.1039/c4cc02211d
65. [65]
  Song Y.K., Lv S.T., Liu X.C.. Energy level tuning of TPB-based holetransporting materials for highly efficient perovskite solar cells[J]. Chem. Commun., 2014,50:15239-15242. doi: 10.1039/C4CC06493C
66. [66]
  Eperon V.M., Burlakov P., Docampo A.. Morphological control for high performance, solution-processed planar heterojunction perovskite solar cells[J]. Adv. Funct. Mater., 2014,24:151-157. doi: 10.1002/adfm.v24.1
67. [67]
  Cheng M., Xu B., Chen C.. Phenoxazine-based small molecule material for efficient perovskite solar cells and bulk heterojunction organic solar cells[J]. Adv. Energy Mater., 2015,51401720. doi: 10.1002/aenm.201401720
68. [68]
  Liu Y.S., Hong Z.R., Chen Q., al et. Perovskite solarcells employingdopant-free organic hole transport materials with tunable energy levels[J]. Adv. Mater., 2016,28:440-446. doi: 10.1002/adma.v28.3
69. [69]
  Liu Y.S., Chen Q., Duan H.S.. A dopant-free organic hole transport material for efficient planar heterojunction perovskite solar cells[J]. J. Mater. Chem. A, 2015,3:11940-11947. doi: 10.1039/C5TA02502H
70. [70]
  Reddy S.S., Gunasekar K., Heo J.H.. Highly efficient organic hole transporting materials for perovskite and organic solar cells with long-term stability[J]. Adv. Mater., 2016,28:686-693. doi: 10.1002/adma.201503729
71. [71]
  Hua Y., Xu B., Liu P.. High conductivity Ag-based metal organic complexes as dopant-free hole-transport materials for perovskite solar cells with high fill factors[J]. Chem. Sci., 2016,7:2633-2638. doi: 10.1039/C5SC03569D
72. [72]
  Zhang J.B., Xu B., Johansson M.B.. Constructive effects of alkyl chains:a strategy to design simple and non-spiro hole transporting materials for highefficiency mixed-ion perovskite solar cells[J]. Adv. Energy Mater., 2016,61502536. doi: 10.1002/aenm.201502536
73. [73]
  Zhang F., Yi C.Y., Wei P.. A novel dopant-free triphenylamine based molecular "butterfly" hole-transport material for highly efficient and stable perovskite solar cells[J]. Adv. Energy Mater., 2016,61600401. doi: 10.1002/aenm.201600401
74. [74]
  Liang P.W., Liao C.Y., Chueh C.C.. Additive enhanced crystallization of solution-processed perovskite for highly efficient planar-heterojunction solar cells[J]. Adv. Mater., 2014,26:3748-3754. doi: 10.1002/adma.v26.22
75. [75]
  Malinkiewicz O., Yella A., Lee Y.H.. Perovskite solar cells employing organic charge-transport layers[J]. Nat. Photonics, 2014,8:128-132.
76. [76]
  Sun S.Y., Salim T., Mathews N.. The origin of high efficiency in lowtemperature solution-processable bilayer organometal halide hybrid solar cells[J]. Energy Environ. Sci., 2014,7:399-407. doi: 10.1039/C3EE43161D
77. [77]
  Docampo P., Ball J.M., Darwich M., Eperon G.E., Snaith H.J.. Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates[J]. Nat. Commun., 2013,42761.
78. [78]
  Xiao Z.G., Bi C., Shao Y.C.. Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers[J]. Energy Environ. Sci., 2014,7:2619-2623. doi: 10.1039/C4EE01138D
79. [79]
  Nie W.Y., Tsai H., Asadpour R.. High-efficiency solution-processed perovskite solar cells with millimeter-scale grains[J]. Science, 2015,347:522-525. doi: 10.1126/science.aaa0472
80. [80]
  Heo J.H., Han H.J., Kim D., Ahn T.K., Im S.H.. Hysteresis-less inverted CH₃NH₃PbI₃ planar perovskite hybrid solarcells with 18.1% powerconversion efficiency[J]. Energy Environ. Sci., 2015,8:1602-1608. doi: 10.1039/C5EE00120J
81. [81]
  Guo Y.L., Liu C., Inoue K.. Enhancement in the efficiency of an organicinorganic hybrid solar cell with a doped P3HT hole-transporting layer on a void-free perovskite active layer[J]. J. Mater. Chem. A, 2014,2:13827-13830. doi: 10.1039/C4TA02976C
82. [82]
  Xue Q.F., Chen G.T., Liu M.Y.. Improving filmformation and photovoltage of highly efficient inverted-type perovskite solar cells through the incorporation of new polymeric hole selective layers[J]. Adv. Energy Mater., 2016,61502021. doi: 10.1002/aenm.201502021
83. [83]
  Zhao D.W., Sexton M., Park H.Y.. High-efficiency solution-processed planar perovskite solar cells with a polymer hole transport layer[J]. Adv. Energy Mater., 2015,51401855. doi: 10.1002/aenm.201401855
84. [84]
  Kim G.W., Kim J., Lee G.Y.. A strategy to design a donor-π-acceptor polymeric hole conductor for an efficient perovskite solar cell[J]. Adv. Energy Mater., 2015,51500471. doi: 10.1002/aenm.201500471
85. [85]
  Jo J.W., Seo M.S., Park M.. Improving performance and stability of flexible planar-heterojunction perovskite solar cells using polymeric holetransport material[J]. Adv. Funct. Mater., 2016,26:4464-4471. doi: 10.1002/adfm.v26.25
86. [86]
  Jeon N.J., Lee J., Noh J.H.. Efficient inorganic-organic hybrid perovskite solar cells based on pyrene arylamine derivatives as hole-transporting materials[J]. J. Am. Chem. Soc., 2013,135:19087-19090. doi: 10.1021/ja410659k
87. [87]
  Sung S.D., Kang M.S., Choi I.T.. 14.8% perovskite solar cells employing carbazole derivatives as hole transporting materials[J]. Chem. Commun., 2014,50:14161-14163. doi: 10.1039/C4CC06716A
88. [88]
  Xue Q.F., Hu Z.C., Liu J.. Highly efficient fullerene/perovskite planar heterojunction solar cells via cathode modification with an aminofunctionalized polymer interlayer[J]. J. Mater. Chem. A, 2014,2:19598-19603. doi: 10.1039/C4TA05352D
89. [89]
  Sun C., Wu Z.H., Yip H.L.. Amino-functionalized conjugated polymer as an efficient electron transport layer for high-performance planarheterojunction perovskite solar cells[J]. Adv. Energy Mater., 2016,61501534. doi: 10.1002/aenm.201501534
90. [90]
  Zhao D.B., Zhu Z.L., Kuo M.Y., Chueh C.C., Jen A.K.Y.. Hexaazatrinaphthylene derivatives:efficient electron-transporting materials with tunable energy levels for inverted perovskite solar cells[J]. Angew. Chem. Int. Ed., 2016,55:8999-9003. doi: 10.1002/anie.201604399
91. [91]
  Wojciechowski K., Leijtens T., Siprova S.. C60 as an efficient n-type compact layer in perovskite solar cells[J]. J. Phys. Chem. Lett., 2015,6:2399-2405. doi: 10.1021/acs.jpclett.5b00902
92. [92]
  Zhu Z.L., Chueh C.C., Lin F., Jen A.K.Y.. Enhanced ambient stability of efficient perovskite solar cells by employing a modified fullerene cathode interlayer[J]. Adv. Sci., 2016,3. doi: 10.1002/advs.201600027
93. [93]
  Liang P.W., Chueh C.C., Williams S.T., Jen A.K.Y.. Roles of fullerene-based interlayers in enhancing the performance of organometal perovskite thinfilm solar cells[J]. Adv. Energy Mater., 2015,5. doi: 10.1002/aenm.201402321
94. [94]
  Grancini G., Santosh Kumar R.S., Abrusci A.. Boosting infrared light harvesting by molecular functionalization of metal oxide/polymer interfaces in efficient hybrid solar cells[J]. Adv. Funct. Mater., 2012,22:2160-2166. doi: 10.1002/adfm.201102360
95. [95]
  Wojciechowski K., Stranks S.D., Abate A.. Heterojunction modification for highly efficient organic-inorganic perovskite solar cells[J]. ACS Nano, 2014,8:12701-12709. doi: 10.1021/nn505723h
96. [96]
  Li C.Z., Huang J., Ju H.. Modulate organic-metal oxide heterojunction via[1, 6] azafulleroid for highly efficient organic solar cells[J]. Adv. Mater., 2016,28:7269-7275. doi: 10.1002/adma.201601161
97. [97]
  Abrusci A., Stranks S.D., Docampo P.. High-performance perovskitepolymer hybrid solar cells via electronic coupling with fullerene monolayers[J]. Nano Lett., 2013,13:3124-3128. doi: 10.1021/nl401044q
98. [98]
  Liu X.D., Lei M., Zhou Y., Song B., Li Y.F.. High performance planar p-i-n perovskite solar cells with crown-ether functionalized fullerene and LiF as double cathode buffer layers[J]. Appl. Phys. Lett., 2015,107063901. doi: 10.1063/1.4928535
99. [99]
  Li Y.W., Zhao Y., Chen Q.. Multifunctional fullerene derivative for interface engineering in perovskite solar cells[J]. J. Am. Chem. Soc., 2015,137:15540-15547. doi: 10.1021/jacs.5b10614
100. [100]
  Li C.Z., Liang P.W., Sulas D.B.. Modulation of hybrid organic-perovskite photovoltaic performance by controlling the excited dynamics of fullerenes[J]. Mater. Horiz., 2015,2:414-419. doi: 10.1039/C5MH00026B
101. [101]
  Yoon H., Kang S.M., Lee J.K., Choi M.. Hysteresis-free low-temperatureprocessed planar perovskite solar cells with 19.1% efficiency[J]. Energy Environ. Sci., 2016,9:2262-2266. doi: 10.1039/C6EE01037G
102. [102]
  Shao S.Y., Abdu-Aguye M., Qiu L.. Elimination of the light soaking effect and performance enhancement in perovskite solar cells using a fullerene derivative[J]. Energy Environ. Sci., 2016,9:2444-2452. doi: 10.1039/C6EE01337F
103. [103]
  Anaraki E.H., Kermanpur A., Steier L.. Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide[J]. Energy Environ. Sci., 2016,9:3128-3134. doi: 10.1039/C6EE02390H
104. [104]
  Li Y.B., Cooper J.K., Liu W.J.. Defective TiO₂ with high photoconductive gain for efficient and stable planar heterojunction perovskite solar cells[J]. Nat. Commun., 2016,712446. doi: 10.1038/ncomms12446
105. [105]
  Giordano F., Abate A., Baena J.P.C.. Enhanced electronic properties in mesoporous TiO₂ via lithium doping for high-efficiency perovskite solarcells[J]. Nat. Commun., 2016,710379. doi: 10.1038/ncomms10379
106. [106]
  Docampo P., Ball J.M., Darwich M., Eperon G.E., Snaith H.J.. Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates[J]. Nat. Commun., 2013,42761.
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沈阳化工大学材料科学与工程学院沈阳 110142