Citation: Xu Hui-Li, Zhang Wei-De. Graphene oxide-MnO₂ nanocomposite-modified glassy carbon electrode as an efficient sensor for H₂O₂[J]. Chinese Chemical Letters, ;2017, 28(1): 143-148. doi: 10.1016/j.cclet.2016.10.008 shu

Graphene oxide-MnO₂ nanocomposite-modified glassy carbon electrode as an efficient sensor for H₂O₂

Xu Hui-Li ,
Zhang Wei-De ^,

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China

Corresponding author: Zhang Wei-De, zhangwd@scut.edu.cn
Received Date: 14 April 2016
Revised Date: 24 June 2016
Accepted Date: 24 June 2016
Available Online: 14 January 2016

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In this study, a new facile preparation method of nanocomposites consisting of graphene oxide and manganese dioxide nanowires (GO/MnO₂ NWs) was developed. The morphology, structure and composition of the resulted products were characterized by transmission electron microscopy, X-ray diffraction and N₂ adsorption and desorption. The GO/MnO₂ nanocomposite was used as an electrode material for non-enzymatic determination of hydrogen peroxide. The proposed sensor exhibits excellent electrocatalytic performance for the determination of hydrogen peroxide in phosphate buffer solution (PBS, pH 7) at an applied potential of 0.75 V. The non-enzymatic biosensor for determination of hydrogen peroxide displayed a wide linear range of 4.90 ÇŒmol L^-1-4.50 mmol L^-1 with a correlation coefficient of 0.9992, a low detection limit of 0.48 ÇŒmol L^-1 and a high sensitivity of 191.22 ÇŒA (mmol L^-1)^-1 cm^-2 (signal/noise, S/N=3). Moreover, the non-enzymatic biosensor shows an excellent selectivity.
- MnO₂,
- Graphene oxide,
- Electroanalysis,
- Nanowires,
- Hydrogen peroxide
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Graphene oxide-MnO₂ nanocomposite-modified glassy carbon electrode as an efficient sensor for H₂O₂