Citation: . Efficient N-heterocyclic carbene nickel pincer complexes catalyzed cross coupling of benzylic ammonium salts with boronic acids[J]. Chinese Chemical Letters, ;2017, 28(2): 350-353. doi: 10.1016/j.cclet.2016.09.006 shu

Efficient N-heterocyclic carbene nickel pincer complexes catalyzed cross coupling of benzylic ammonium salts with boronic acids

Received Date: 25 July 2016
Revised Date: 29 August 2016
Accepted Date: 9 September 2016
Available Online: 21 February 2016

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Pyridine-bridged bis-benzimidazolylidene nickel complexes exhibited very high catalytic activity toward cross coupling of inactive (hetero)aryl benzylic ammonium salts with (hetero)aryl and alkenyl boronic acids under mild reaction conditions. Even at 2 mol% catalyst loading, a wide range of substrates for both coupling partners with different steric and electronic properties were well tolerated.
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