Citation: Liu Ling-Yang, Zhang Xu, Li Hong-Xia, Liu Bao, Lang Jun-Wei, Kong Ling-Bin, Yan Xing-Bin. Synthesis of Co-Ni oxide microflowers as a superior anode for hybrid supercapacitors with ultralong cycle life[J]. Chinese Chemical Letters, ;2017, 28(2): 206-212. doi: 10.1016/j.cclet.2016.07.027 shu

Synthesis of Co-Ni oxide microflowers as a superior anode for hybrid supercapacitors with ultralong cycle life

Liu Ling-Yang ^a,c ,
Zhang Xu ^c ,
Li Hong-Xia ^c ,
Liu Bao ^c ,
Lang Jun-Wei ^c ,
Kong Ling-Bin ^a,b,, ,
Yan Xing-Bin ^c,,

a.
State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
b.
School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China
c.
Laboratory of Clean Energy Chemistry and Materials, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Corresponding author: Kong Ling-Bin, konglb@lut.cn Yan Xing-Bin, xbyan@licp.cas.cn
Received Date: 30 May 2016
Revised Date: 26 June 2016
Accepted Date: 4 July 2016
Available Online: 29 February 2016

Figures(4)

Li-ion hybrid capacitors (LIHCs), composing of a lithium-ion battery (LIB) type anode and a supercapacitor (SC) type cathode, gained worldwide popularity due to harmonious integrating the virtues of high energy density of LIBs with high power density of SCs. Herein, nanoflakes composed microflower-like Co-Ni oxide (CoNiO) was successfully synthesized by a simple co-precipitation method. The atomic ratio of as-synthesized CoNiO is determined to be 1:3 through XRD and XPS analytical method. As a typical battery-type material, CoNiO and capacitor-type activated polyanilinederived carbon (APDC) were used to assemble LIHCs as the anode and cathode materials, respectively. As a result, when an optimized mass ratio of CoNiO and APDC was 1:2, CoNiO//APDC LIHC could deliver a maximum energy density of 143 Wh kg^-1 at a working voltage of 1-4 V. It is worth mentioning that the LIHC also exhibits excellent cycle stability with the capacitance retention of 78.2% after 15,000 cycles at a current density of 0.5 A g^-1.
- Li-ion hybrid capacitor,
- Energy storage device,
- Co-precipitation method,
- Cobalt nickel oxide,
- APDC,
- Long cycle life
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