Citation: Leng Xin-Li, Song Li-Li, Lu Yan, Liu Xiao-Qing, Wang Li. Observations of carbon-carbon coupling of 4, 4-dibromo-pterphenyl on Cu (110) surface at molecular level[J]. Chinese Chemical Letters, ;2017, 28(1): 24-28. doi: 10.1016/j.cclet.2016.06.036 shu

Observations of carbon-carbon coupling of 4, 4-dibromo-pterphenyl on Cu (110) surface at molecular level

Leng Xin-Li ^a ,
Song Li-Li ^b ,
Lu Yan ^a ,
Liu Xiao-Qing ^a,, ,
Wang Li ^a

a.
Department of Physics, Nanchang University, Nanchang 330031, China
b.
Department of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: Liu Xiao-Qing, liuxiaoqing@ncu.edu.cn
Received Date: 25 May 2016
Revised Date: 14 June 2016
Accepted Date: 24 June 2016
Available Online: 2 January 2016

Figures(3)

The carbon-carbon couplings of 4, 4"-dibromo-p-terphenyl (DBTP) on Cu (110) surface have been investigated at a single molecular level by scanning tunneling microscopy. After annealing at 353 K, a mixture of parallel non-organometallic and organometallic intermediates of DBTP molecules along the[1-10] direction of the surface has been observed. Further annealing at 393 K causes one group of molecules to form oligomers with para-para and para-meta motifs via Ullmann reaction and the other group of molecules to synthesize oligomers with meta-meta motifs via direct carbon-carbon coupling reaction. Statistical results directly reveal that the occurrence of reaction type is strongly related to the initial binding configuration of DBTP molecules.
- Carbon-carbon coupling,
- Ullmann coupling,
- Organometallic intermediate,
- Selective C-H activation,
- Oligomer
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