Citation: Deng Chuan-Dong, Qiao Yu-Jia, Chen Qing-De, Shen Xing-Hai. Preparation and characterization of single crystals[Ln (TBPO)₄(NO₃)₂]NTf₂ (Ln=Eu, Gd)[J]. Chinese Chemical Letters, ;2017, 28(1): 19-23. doi: 10.1016/j.cclet.2016.06.020 shu

Preparation and characterization of single crystals[Ln (TBPO)₄(NO₃)₂]NTf₂ (Ln=Eu, Gd)

Beijing National Laboratory for Molecular Sciences (BNLMS), Fundamental Science on Radiochemistry and Radiation Chemistry Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: Shen Xing-Hai, xshen@pku.edu.cn
Received Date: 11 May 2016
Revised Date: 31 May 2016
Accepted Date: 6 June 2016
Available Online: 21 January 2016

Figures(7)

Two single crystals[Ln (TBPO)₄(NO₃)₂]NTf₂ (Ln=Eu, Gd) were prepared and characterized by element analysis, single crystal X-ray diffraction, PXRD, FT-IR, TGA and fluorescence spectroscopy. The two compounds have similar coordinate structures, in which the central metal ion is coordinated by four TBPO (Tri-n-butylphosphine oxide) molecules and two bidentate nitrates, while NTf₂^-(bis (trifluor-(bis (trifluoromethylsulfonyl) imide anion) acts as the counter anion. The packing modes of the two crystals are same. The two single crystals are the focus on 8-coordinate tetra-TRPO complexes (TRPO is Trialkyphosphine oxides).
- Tri-n-butylphosphine oxide,
- Europium,
- Gadolinium,
- Single crystal
1. [1]
  Massabni A.M.G., Gibran M.L.R., Serra O.A.. Phosphine oxides complexes of neodymium (Ⅲ) nitrate[J]. Inorg. Nucl. Chem. Lett., 1978,14:419-427. doi: 10.1016/0020-1650(78)80008-7
2. [2]
  Hunter A.P., Lees A.M.J., Platt A.W.G.. Synthesis, structures and mass spectrometry of lanthanide nitrate complexes with tricyclohexylphosphine oxide[J]. Polyhedron, 2007,26:4865-4876. doi: 10.1016/j.poly.2007.06.023
3. [3]
  Bowden A., Horton P.N., Platt A.W.G.. Lanthanide nitrate complexes of tri-isobutylphosphine oxide:solid state and CD₂Cl₂ solution structures[J]. Inorg. Chem., 2011,50:2553-2561. doi: 10.1021/ic102385p
4. [4]
  Bowden A., Coles S.J., Pitak M.B., Platt A.W.G.. Complexes of lanthanide nitrates with tri-isopropylphosphine oxide[J]. Polyhedron, 2014,68:258-264. doi: 10.1016/j.poly.2013.10.028
5. [5]
  Manchanda V.K., Chander K., Singh N.P., Nair G.M.. Complexes of lanthanides with trioctylphosphine oxide and tributylphosphine oxide[J]. J. Inorg. Nucl. Chem., 1977,39:1039-1041. doi: 10.1016/0022-1902(77)80260-1
6. [6]
  Bowden A., Singh K., Platt A.W.G.. Lanthanide nitrate complexes with triethylphosphine oxide. Solid state and solution properties[J]. Polyhedron, 2012,42:30-35. doi: 10.1016/j.poly.2012.04.021
7. [7]
  Bowden A., Coles S.J., Pitak M.B., Platt A.W.G.. Complexes of lanthanide nitrates with tri tert butylphosphine oxide[J]. Inorg. Chem., 2012,51:4379-4389. doi: 10.1021/ic300142r
8. [8]
  Platt A.W.G., Singh K.. The interactions between the sterically demanding trimesitylphosphine oxide and trimesityphosphine with scandium and selected lanthanide ions[J]. J. Mol. Struct., 2016,1111:180-184. doi: 10.1016/j.molstruc.2016.01.073
9. [9]
  Baba Y., Kubota F., Kamiya N., Goto M.. Recent advances in extraction and separation of rare-earth metals using ionic liquids[J]. J. Chem. Eng. Jpn., 2011,44:679-685. doi: 10.1252/jcej.10we279
10. [10]
  Sun X.Q., Luo H.M., Dai S.. Ionic liquids-based extraction:a promising strategy for the advanced nuclear fuel cycle[J]. Chem. Rev., 2012,112:2100-2128. doi: 10.1021/cr200193x
11. [11]
  Dietz M.L.. Ionic liquids as extraction solvents:where do we stand?[J]. Sep. Sci. Technol., 2006,41:2047-2063. doi: 10.1080/01496390600743144
12. [12]
  Liu H.W., Yang T., Chen Q.D., Shen X.H.. Extraction behaviors of ionic liquid systems and application perspectives in reprocessing of spent nuclear fuel[J]. J. Nucl. Radiochem., 2015,37:286-309.
13. [13]
  Matsumiya M., Kikuchi Y., Yamada T., Kawakami S.. Extraction of rare earth ions by tri-n-butylphosphate/phosphonium ionic liquids and the feasibility of recovery by direct electrodeposition[J]. Sep. Purif. Technol., 2014,130:91-101. doi: 10.1016/j.seppur.2014.04.021
14. [14]
  Ma G.L., Yuan W.J., Dong Z.. Extraction of lanthanides from nitric acid solution using isobutyl-BTP/ionic liquid system[J]. Nucl. Sci. Technol, 2015,26S10305.
15. [15]
  Turgis R., Arrachart G., Dubois V.. Performances and mechanistic investigations of a triphosphine trioxide/ionic liquid system for rare earth extraction[J]. Dalton Trans., 2016,45:1259-1268. doi: 10.1039/C5DT03072B
16. [16]
  H.W. Liu, Extraction Study of U and Eu in Ionic Liquid Systems and the Synthesis of Europium-Containing Ionic Liquid Complexes, Master Thesis, Peking University, Beijing, 2015.
17. [17]
  Levason W., Newman E.H., Webster M.. Tetrakis (triphenylphosphine oxide) complexes of the lanthanide nitrates; synthesis, characterisation and crystal structures of[J]. Polyhedron, 2000,19:2697-2705. doi: 10.1016/S0277-5387(00)00588-X
18. [18]
  T.X. Sun, Application of Ionic Liquids in the Extraction of Sr, Cs, U and Tc, Ph.D. Thesis, Peking University, Beijing, 2013.
19. [19]
  T.X. Sun, Z.M. Wang, X.H. Shen, Crystallization of cesium complex containing bis (2-propyloxy) calix [4] crown-6 and bis[(trifluoromethyl) sulfonyl] imide, Inorg. Chim. Acta 390(2012) 8-11.
20. [20]
  Li H.F., Zheng B., Huang K.W.. A new class of PN³-pincer ligands for metal-ligand cooperative catalysis[J]. Coord. Chem. Rev. 293-, 2015,294:116-138.
21. [21]
  Chen F.S., Chen G., Liu T.. Controllable fabrication and optical properties of uniform gadolinium oxysulfate hollow spheres[J]. Sci. Rep., 2015,517934. doi: 10.1038/srep17934
22. [22]
  Xue J.H., Hua X.H., Yang L.M.. Synthesis, crystal structures and luminescence properties of europium and terbium picolinamide complexes[J]. Chin. Chem. Lett., 2014,25:887-891. doi: 10.1016/j.cclet.2014.01.012
23. [23]
  Sun W.J., Wu Y.X., Zhang H.G., Zhu L., Gao S.L.. Spectra of rare earth complexes with salicylate[J]. Acta Photonica Sin., 2006,35:1593-1596.
1. [1]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
2. [2]
  Hongzhi Zhang , Hong Li , Asif Ali Haider , Junpeng Li , Zhi Xie , Hongming Jiang , Conglin Liu , Rui Wang , Jing Zhu . An unexpected role of lanthanide substitution in thermally responsive phosphors NaLnTe2O7: Eu3+ (Ln = Y and Gd). Chinese Journal of Structural Chemistry, 2025, 44(2): 100509-100509. doi: 10.1016/j.cjsc.2024.100509
3. [3]
  Min Chen , Boyu Peng , Xuyun Guo , Ye Zhu , Hanying Li . Polyethylene interfacial dielectric layer for organic semiconductor single crystal based field-effect transistors. Chinese Chemical Letters, 2024, 35(4): 109051-. doi: 10.1016/j.cclet.2023.109051
4. [4]
  Zhenfei Tang , Yunwu Zhang , Zhiyuan Yang , Haifeng Yuan , Tong Wu , Yue Li , Guixiang Zhang , Xingzhi Wang , Bin Chang , Dehui Sun , Hong Liu , Lili Zhao , Weijia Zhou . Iron-doping regulated light absorption and active sites in LiTaO₃ single crystal for photocatalytic nitrogen reduction. Chinese Chemical Letters, 2025, 36(3): 110107-. doi: 10.1016/j.cclet.2024.110107
5. [5]
  Chunhui Zhang , Jie Wang , Jieyang Zhan , Runmin Yang , Guanggang Gao , Jiayuan Zhang , Linlin Fan , Mengqi Wang , Hong Liu . Highly sensitive hydrazine detection through a novel Raman scattering quenching mechanism enabled by a crystalline and noble metal–free polyoxometalate substrate. Chinese Chemical Letters, 2025, 36(3): 109719-. doi: 10.1016/j.cclet.2024.109719
6. [6]
  Yueshuai Xu , Wei Liu , Xudong Chen , Zhikun Zheng . 水相中制备共价有机框架单晶的实验教学设计. University Chemistry, 2025, 40(6): 256-265. doi: 10.12461/PKU.DXHX202408045
7. [7]
  Junqing Wu , Yiyang Zhang , Qingqing Hong , Hui Yang , Lifeng Zhang , Ming Zhang , Lei Yu . Organometallic modification of silica with europium endowing the fluorescence properties: The key technique for numerical quality monitoring. Chinese Chemical Letters, 2025, 36(4): 110165-. doi: 10.1016/j.cclet.2024.110165
8. [8]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
9. [9]
  Wenli Xu , Yingzhao Zhang , Rui Wang , Chenyang Liu , Jialin Liu , Xiangyu Huo , Xinying Liu , He Zhang , Jianxu Ding . In-situ passivating surface defects of ultra-thin MAPbBr3 perovskite single crystal films for high performance photodetectors. Chinese Journal of Structural Chemistry, 2025, 44(1): 100454-100454. doi: 10.1016/j.cjsc.2024.100454
10. [10]
  Qiuting Zhang , Fan Wu , Jin Liu , Hang Su , Yanhui Zhong , Zian Lin . Facile synthesis of single-crystal 3D covalent organic frameworks as stationary phases for high-performance liquid chromatographic separation. Chinese Chemical Letters, 2025, 36(8): 110649-. doi: 10.1016/j.cclet.2024.110649
11. [11]
  Yuming Shu , Hanghang Lei , Jiangnan Huang , Qing Pan , Baichao Zhang , Yixin Xu , Ye Zhou , Guorong Hu , Yanbing Cao , Guoqiang Zou , Wentao Deng , Zhongdong Peng , Hongshuai Hou , Di Chen , Xiaobo Ji . Enabling superior performance in brick-like single-crystal LiMn₂O₄ via BaO flux. Chinese Chemical Letters, 2025, 36(9): 110345-. doi: 10.1016/j.cclet.2024.110345
12. [12]
  Yi Chen , Hua-Pan Wu , Zheng-Wei Guo , Xin-Xiong Li , Ping-Wei Cai , Shou-Tian Zheng . Construction of a diverting polyoxotungstate based on 3d-5p heterometallic cluster for high-performance single-crystal proton conduction. Chinese Chemical Letters, 2025, 36(11): 110552-. doi: 10.1016/j.cclet.2024.110552
13. [13]
  Li Li , Lin-Lin Zhang , Yansha Gao , Lu-Ying Duan , Wuying Yang , Xigen Huang , Yanping Hong , Jiaxin Hong , Lin Yuan , Limin Lu . Target self-calibration ratiometric fluorescent sensor based on facile-synthesized europium metal-organic framework for multi-color visual detection of levofloxacin. Chinese Chemical Letters, 2025, 36(7): 110436-. doi: 10.1016/j.cclet.2024.110436
14. [14]
  Xinyuan Li , Zhuozhu Li , Wenzhong Huang , Jiantao Li , Wei Zhang , Shihao Feng , Hao Fan , Zhuo Chen , Sungsik Lee , Congcong Cai , Liang Zhou . Solvent-free synthesis of Co single atom and nanocluster decorated N-doped carbon for efficient oxygen reduction. Chinese Chemical Letters, 2025, 36(9): 110716-. doi: 10.1016/j.cclet.2024.110716
15. [15]
  Xinxin Zhang , Zhijian Liang , Xu Zhang , Qian Guo , Ying Xie , Lei Wang , Honggang Fu . Electronic modulation of VN on Co_5.47N as tri-functional electrocatalyst for constructing zinc-air battery to drive water splitting. Chinese Chemical Letters, 2025, 36(5): 109935-. doi: 10.1016/j.cclet.2024.109935
16. [16]
  Wen-Xuan Shao , Jianyuan Wu , Gaojie Li , Yi-Hao Min , Qiu-Shuang Hu , Yu Liu , Weimin Ci , Bi-Feng Yuan . Quantitative analysis of N⁶-methyladenine at single-base resolution in mitochondrial DNA of hepatocellular carcinoma by deaminase-mediated sequencing. Chinese Chemical Letters, 2025, 36(10): 110747-. doi: 10.1016/j.cclet.2024.110747
17. [17]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
18. [18]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
19. [19]
  Yukai Tong , Zhijun Wu , Bo Zhou , Min Hu , Anpei Ye . Surface tension of single suspended aerosol microdroplets. Chinese Chemical Letters, 2024, 35(4): 109062-. doi: 10.1016/j.cclet.2023.109062
20. [20]
  Kun Tang , Yu-Wu Zhong . Water reduction by an organic single-chromophore photocatalyst. Chinese Journal of Structural Chemistry, 2024, 43(8): 100376-100376. doi: 10.1016/j.cjsc.2024.100376

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1710)
HTML views(263)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and characterization of single crystals[Ln (TBPO)4(NO3)2]NTf2 (Ln=Eu, Gd)

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and characterization of single crystals[Ln (TBPO)₄(NO₃)₂]NTf₂ (Ln=Eu, Gd)