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Citation: Xu Yue-Ling, Gao Qiang, Zhao Meng, Zhang Huan-Jun, Zhang Ying-Hui, Chang Ze. Impact of the flexibility of pillar linkers on the structure and CO2 adsorption property of "pillar-layered" MOFs[J]. Chinese Chemical Letters, ;2017, 28(1): 55-59. doi: 10.1016/j.cclet.2016.06.006 shu

Impact of the flexibility of pillar linkers on the structure and CO2 adsorption property of "pillar-layered" MOFs

  • a.

    School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China

  • b.

    Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

  • Corresponding author: Zhang Ying-Hui, zhangyhi@nankai.edu.cn
  • Received Date: 28 April 2016
    Revised Date: 17 May 2016
    Accepted Date: 25 May 2016
    Available Online: 8 January 2016

Figures(5)

  • A new metal-organic framework {[Zn2(bpta)(bpy-ee)(H2O)2]·x solve}n (1) (H4bpta=biphenyl-2, 2', 6, 6'-tetracarboxylic acid and bpy-ee=1, 2-bis (4-pyridyl) ethylene) has been obtained under hydrothermal condition, and structurally characterized by single-crystal X-ray diffraction. Complex 1 reveals a threedimensional (3D) "pillar-layered" framework with non-flexible linker, in which some different structure characters can be found compared to that of some related other "pillar-layered" MOFs based on flexible pillar linkers. It demonstrates the impact of the flexibility of pillar linker on the final structure in this system. In addition, the selective CO2 adsorption performance of 1 was also investigated.
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