Citation: Zhao Shu-Yang, Wang Sheng-Ping, Zhao Yu-Jun, Ma Xin-Bin. An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over well-shaped CeO₂[J]. Chinese Chemical Letters, ;2017, 28(1): 65-69. doi: 10.1016/j.cclet.2016.06.003 shu

An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over well-shaped CeO₂

Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Tianjin University; Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Corresponding author: Wang Sheng-Ping, spwang@tju.edu.cn
Received Date: 27 April 2016
Revised Date: 14 May 2016
Accepted Date: 23 May 2016
Available Online: 8 January 2016

Figures(5)

The mechanism of dimethyl carbonate (DMC) formation from CO₂ and methanol is investigated using three well-shaped CeO₂ catalysts, nanorod, nanocube and octahedron, which are packed with different crystal planes. In situ Fourier Transform Infrared Spectroscopy (FTIR) is employed to probe each reaction step in the DMC synthesis. The number of -OH groups and the species of CO₂ adsorptions on ceria surface have significant influence on the activity of ceria with different morphologies. Rod-ceria has favorable catalytic activity because of the large amount of -OH groups and the formation of bidentate carbonate species.
- Dimethyl carbonate,
- CeO₂,
- -OH,
- Bidentate carbonate,
- Crystal planes
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over well-shaped CeO2

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通讯作者: 陈斌, bchen63@163.com

An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over well-shaped CeO₂