Citation: Xie Li-Qing, Zhang Yan-Hui, Gao Fei, Wu Quan-An, Xu Piao-Yang, Wang Shan-Shan, Gao Ning-Ning, Wang Qing-Xiang. A highly sensitive dopamine sensor based on a polyaniline/reduced graphene oxide/Nafion nanocomposite[J]. Chinese Chemical Letters, ;2017, 28(1): 41-48. doi: 10.1016/j.cclet.2016.05.015 shu

A highly sensitive dopamine sensor based on a polyaniline/reduced graphene oxide/Nafion nanocomposite

a.
College of Chemistry and Environment, Minnan Normal University, Zhangzhou 363000, China
b.
Fujian Provincial Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou 363000, China

Received Date: 7 March 2016
Revised Date: 26 April 2016
Accepted Date: 7 May 2016
Available Online: 27 January 2016

Figures(8)

A nanocomposite of polyaniline/reduced graphene oxide (PANI-rGO) was synthesized using a hydrothermal method. The product was characterized by FT-IR, Raman spectra, XRD, SEM and TEM. Then the hybrid material of PANI-rGO and Nafion (PANI-rGO-NF) was prepared and used to modify glassy carbon electrode for the trace determination of dopamine (DA) employing differential pulse voltammetry (DPV). It was found that the hybrid material showed good catalytic activity toward the oxidation of DA, and no response to ascorbic acid (AA) and uric acid (UA) was observed, suggesting a high selectivity of the sensor toward DA. The peak currents were linearly correlated with the concentration of DA in the range from 0.05 μmol/L to 60.0 μmol/L (R=0.996) and 60.0 μmol/L to 180.0 μmol/L (R=0.996) with a detection limit of 0.024 μmol/L (S/N=3). The modified electrode also exhibited excellent repeatability and stability.
- Dopamine,
- Graphene oxide,
- Electrochemical,
- Nafion,
- Polyaniline
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