Citation: Wen-Zhu Zhang, Zhong-Bo Du, Bo Song, Zhi-Qiang Ye, Jing-Li Yuan. Development of a triple channel detection probe for hydrogen peroxide[J]. Chinese Chemical Letters, ;2015, 26(12): 1465-1469. doi: 10.1016/j.cclet.2015.10.022 shu

Development of a triple channel detection probe for hydrogen peroxide

1.
State Key Laboratory of Fine Chemicals, School of Chemistry, Dalian University of Technology, Dalian 116024, China

Corresponding author: Zhi-Qiang Ye,
Received Date: 17 August 2015
Available Online: 27 October 2015

The rapid and reliable measurement of hydrogen peroxide (H₂O₂) is imperative for many areas of technology, including pharmaceutical, clinical, food industry and environmental applications. In this work, a novel multifunctional complex, [Ru(bpy)₂(luminol-bpy)](PF₆)₂ (bpy: 2,20'-bipyridine), was designed and synthesized by incorporating a Ru(II) complex with a luminal group. In the presence of horseradish peroxidase (HRP), reaction of [Ru(bpy)₂(luminol-bpy)]²⁺ with H₂O₂ can be monitored by three sensing channels including photoluminescence (PL), chemiluminiscence (CL) and eletrochemiluminiscence (ECL). The quantitative assays for H₂O₂ in aqueous solutions using [Ru(bpy)₂(Luminalbpy)]( PF₆)₂ as a probe were established with PL, ECL and CL signal output modes, respectively.
- Hydrogen peroxide
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沈阳化工大学材料科学与工程学院沈阳 110142