Citation: Xiao-Yan Ren, Le-Hui Lu. Luminescent nanoscale metal-organic frameworks for chemical sensing[J]. Chinese Chemical Letters, ;2015, 26(12): 1439-1445. doi: 10.1016/j.cclet.2015.10.014 shu

Luminescent nanoscale metal-organic frameworks for chemical sensing

Xiao-Yan Ren ^, ,
Le-Hui Lu

1.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: Xiao-Yan Ren,
Received Date: 26 August 2015
Available Online: 19 October 2015

Metal-organic frameworks (MOFs) are a fascinating class of crystalline materials constructed from selfassembly of metal cations/clusters and organic ligands. Both metal and organic components can be used to generate luminescence, and can further interact via antenna effect to increase the quantum yield, providing a versatile platform for chemical sensing based on luminescence emission. Moreover, MOFs can be miniaturized to nanometer scale to form nano-MOF (NMOF) materials, which exhibit many advantages over conventional bulk MOFs in terms of the facile tailorability of compositions, sizes and morphologies, the high dispersity in a wide variety of medium, and the intrinsic biocompatibility. This review will detail the development of NMOF materials as chemical sensors, including the synthetic methodologies for designing NMOF sensory materials, their luminescent properties and potential sensing applications.
- Luminescence
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