Citation: Liang Deng, Wen-Hui Yang, Shao-Xiong Zhou, Ji-Tao Chen. Effect of carbon nanotubes addition on electrochemical performance and thermal stability of Li₄Ti₅O₁₂ anode in commercial LiMn₂O₄/Li₄Ti₅O₁₂ full-cell[J]. Chinese Chemical Letters, ;2015, 26(12): 1529-1534. doi: 10.1016/j.cclet.2015.06.009 shu

Effect of carbon nanotubes addition on electrochemical performance and thermal stability of Li₄Ti₅O₁₂ anode in commercial LiMn₂O₄/Li₄Ti₅O₁₂ full-cell

1.
a Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China;
b China Iron & Steel Research Institute Group, Advanced Technology & Materials Co.
b China Iron & Steel Research Institute Group, Advanced Technology & Materials Co., Ltd., Beijing 100081, China;
3.
c Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: Liang Deng,
Received Date: 7 April 2015
Available Online: 29 May 2015

Li₄Ti₅O₁₂ (LTO)/carbon nanotubes (CNTs) composite material is synthesized based on a solid-state method by sand-milling, spray-drying and calcining at 850 ℃ under N₂ flow. The LTO/CNTs samples with 1 wt% and 3 wt% weight ratio of CNTs addition and the pristine LTO sample are prepared. The rate performance and the thermal stability of these samples are investigated based on LiMn₂O₄ (LMO)/LTO full-cell. The results show that theweight ratio of CNTs addition has distinct effect on LTO performances. The composite materials of LTO composited CNTs have better performance at high-rate due to the intercalation enhancement by conductive network of CNTs. At second, the overcharging temperature response of the cell's surface with 1 wt% CNTs addition is the lowest. The particle size distribution is measured and the most uniform particles are obtained with 1 wt% CNTs addition. This trend could explain that the mediumquantity of CNTs is optimal to improve the heat and mass transfer and prevent the problems of crystallite growing interference and aggregation during the calcination process.
- Lithium titanate
1. [1]
  [1] W. Wei, L.X. Song, L. Guo, SnO2 hollow nanospheres assembled by single layer nanocrystals as anode material for high performance Li ion batteries, Chin. Chem. Lett. 26 (2015) 124-128.
2. [2]
  [2] Y.J. Li, C.X. Zhou, S. Chen, F. Wu, L. Hong, Nd³⁺-doped Li₃V₂(PO₄)₃ cathode material with high rate capability for Li-ion batteries, Chin. Chem. Lett. (2015), http:// dx.doi.org/10.1016/j.cclet.2015.03.013.
3. [3]
  [3] K. Wu, J. Yang, Y. Zhang, C.Y. Wang, D.Y. Wang, Investigation on Li₄Ti₅O₁₂ batteries developed for hybrid electric vehicle, J. Appl. Electrochem. 42 (2012) 989-995.
4. [4]
  [4] L.J. Chang, S.H. Luo, H.L. Zhang, et al., Synthesis and performance of Li₄Ti₅O₁₂ anode materials using the PVP-assisted combustion method, Chin. Chem. Lett. 25 (2014) 1569-1572.
5. [5]
  [5] T. Ohzuku, A. Ueda, N. Yamamota, Zero-strain insertion material of Li[Li_1/3Ti_5/3]O₄ for rechargeable lithium cells, J. Electrochem. Soc. 142 (1995) 1431-1435.
6. [6]
  [6] K. Ariyoshi, R. Yamato, T. Ohzuku, Zero-strain insertion mechanism of Li[Li_1/3Ti_{5/ 3}]O₄ for advanced lithium-ion (shuttlecock) batteries, Electrochim. Acta 51 (2005) 1125-1129.
7. [7]
  [7] J.L. Allen, T.R. Jow, J. Wolfenstine, Low temperature performance of nanophase Li₄Ti₅O₁₂, J. Power Sources 159 (2006) 1340-1345.
8. [8]
  [8] M. Marinaro, F. Nobili, A. Birrozzi, et al., Improved low-temperature electrochemical performance of Li₄Ti₅O₁₂ composite anodes for Li-ion batteries, Electrochim. Acta 109 (2013) 207-213.
9. [9]
  [9] Y.R. Zhu, L.C. Yin, T.F. Yi, et al., Electrochemical performance and lithium-ion intercalation kinetics of submicron-sized Li₄Ti₅O₁₂ anode material, J. Alloys Compd. 547 (2013) 107-112.
10. [10]
  [10] Z.W. Zhang, L.Y. Cao, J.F. Huang, et al., Temperature effect on spinel Li₄Ti₅O₁₂ as anode materials for lithium ion batteries, Electrochim. Acta 88 (2013) 443-446.
11. [11]
  [11] X. Li, P.X. Huang, Y. Zhou, et al., A novel Li₄Ti₅O₁₂/graphene/carbon nano-tubes hybrid material for high rate lithium ion batteries, Mater. Lett. 133 (2014) 289- 292.
12. [12]
  [12] M. Vujković, I. Stojković, M. Mitrić, S. Mentus, N. Cvjetićanin, Hydrothermal synthesis of Li₄Ti₅O₁₂/C nanostructured composites: morphology and electrochemical performance, Mater. Res. Bull. 48 (2013) 218-223.
13. [13]
  [13] L.P. Wang, H.Q. Zhang, Q.J. Deng, et al., Superior rate performance of Li₄Ti₅O₁₂/ TiO₂/C/CNTs composites via microemulsion-assisted method as anodes for lithium ion battery, Electrochim. Acta 142 (2014) 202-207.
14. [14]
  [14] C.F. Lin, B. Ding, Y.L. Xin, et al., Advanced electrochemical performance of Li₄Ti₅O₁₂-based materials for lithium-ion battery: synergistic effect of doping and compositing, J. Power Sources 248 (2014) 1034-1041.
15. [15]
  [15] X.M. Liu, Z.D. Huang, S.W. Oh, et al., Carbon nanotube (CNT)-based composites as electrode material for rechargeable Li-ion batteries: a review, Compos. Sci. Technol. 72 (2012) 121-144.
16. [16]
  [16] L. Li, H. Yang, D.X. Zhou, Y.Y. Zhou, Progress in application of CNTs in lithium-ion batteries, J. Nanomater. (2014) 187891.
17. [17]
  [17] W.X. Bao, C.C. Zhu, Study of thermal conduction of carbon nanotube by molecular dynamics, Acta Phys. Sin. 55 (2006) 3552-3557.
18. [18]
  [18] Y. Cuenca, A. Vernet, M. Vallè s, Thermal conductivity enhancement of the binary mixture (NH₃ + LiNO₃) by the addition of CNTs, Int. J. Refrig. 41 (2014) 113-120.
19. [19]
  [19] L.F. Shen, C.Z. Yuan, H.J. Luo, et al., In situ growth of Li₄Ti₅O₁₂ on multi-walled carbon nanotubes: novel coaxial nanocables for high rate lithium ion batteries, J. Mater. Chem. 21 (2011) 761-767.
20. [20]
  [20] H.F. Ni, L.Z. Fan, Nano-Li₄Ti₅O₁₂ anchored on carbon nanotubes by liquid phase deposition as anode material for high rate lithium-ion batteries, J. Power Sources 214 (2012) 195-199.
21. [21]
  [21] Z.G. Wang, Z.X. Wang, W.J. Peng, H.J. Guo, X.H. Li, An improved solid-state reaction to synthesize Zr-doped Li₄Ti₅O₁₂ anode material and its application in LiMn₂O₄/ Li₄Ti₅O₁₂ full-cell, Ceram. Int. 40 (2014) 10053-10059.
22. [22]
  [22] A.D. Pasquiera, C.C. Huang, T. Spitler, Nano Li₄Ti₅O₁₂-LiMn₂O₄ batteries with high power capability and improved cycle-life, J. Power Sources 186 (2009) 508-514.
23. [23]
  [23] Y.R. Jhan, J.G. Duh, Synthesis of entanglement structure in nanosized Li₄Ti₅O₁₂/ multi-walled carbon nanotubes composite anode material for Li-ion batteries by ball-milling-assisted solid-state reaction, J. Power Sources 198 (2012) 294-297.
24. [24]
  [24] H.Y. Zhang, Y.T. Chen, J. Li, C.H. He, Y.M. Chen, Li₄Ti₅O₁₂/CNTs composite anode material for large capacity and high-rate lithium ion batteries, Int. J. Hydrogen Energy 39 (2014) 16096-16102.
25. [25]
  [25] S.J. Bae, H.D. Song, I. Nam, et al., Quantitative performance analysis of graphite- LiFePO4 battery working at low temperature, Chem. Eng. Sci. 118 (2014) 74-82.
26. [26]
  [26] X.N. Feng, M. Fang, X.M. He, et al., Thermal runaway features of large format prismatic lithium ion battery using extended volume accelerating rate calorimetry, J. Power Sources 255 (2014) 294-301.
27. [27]
  [27] M.G. Ouyang, D.S. Ren, L.G. Lu, et al., Overcharge-induced capacity fading analysis for large format lithium-ion batteries with Li_yNi_1/3Co_1/3Mn_1/3O₂ + Li_yMn₂O₄ composite cathode, J. Power Sources 279 (2015) 626-635.
1. [1]
  Mengwen Wang , Qintao Sun , Yue Liu , Zhengan Yan , Qiyu Xu , Yuchen Wu , Tao Cheng . Impact of lithium nitrate additives on the solid electrolyte interphase in lithium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(2): 100203-100203. doi: 10.1016/j.cjsc.2023.100203
2. [2]
  Ting Hu , Yuxuan Guo , Yixuan Meng , Ze Zhang , Ji Yu , Jianxin Cai , Zhenyu Yang . Uniform lithium deposition induced by copper phthalocyanine additive for durable lithium anode in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108603-. doi: 10.1016/j.cclet.2023.108603
3. [3]
  Tao Wei , Jiahao Lu , Pan Zhang , Qi Zhang , Guang Yang , Ruizhi Yang , Daifen Chen , Qian Wang , Yongfu Tang . An intermittent lithium deposition model based on bimetallic MOFs derivatives for dendrite-free lithium anode with ultrahigh areal capacity. Chinese Chemical Letters, 2024, 35(8): 109122-. doi: 10.1016/j.cclet.2023.109122
4. [4]
  Shu Lin , Kezhen Qi . Phase-dependent lithium-alloying reactions for lithium-metal batteries. Chinese Chemical Letters, 2024, 35(4): 109431-. doi: 10.1016/j.cclet.2023.109431
5. [5]
  Dong Sui , Jiayi Liu . Constriction-susceptible lithium support for fast cycling of solid-state lithium metal battery. Chinese Chemical Letters, 2025, 36(2): 110417-. doi: 10.1016/j.cclet.2024.110417
6. [6]
  Jiale Zheng , Mei Chen , Huadong Yuan , Jianmin Luo , Yao Wang , Jianwei Nai , Xinyong Tao , Yujing Liu . Electron-microscopical visualization on the interfacial and crystallographic structures of lithium metal anode. Chinese Chemical Letters, 2024, 35(6): 108812-. doi: 10.1016/j.cclet.2023.108812
7. [7]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
8. [8]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
9. [9]
  Jia-hui Li , Jinkai Qiu , Cheng Lian . Lithium-ion rapid transport mechanism and channel design in solid electrolytes. Chinese Journal of Structural Chemistry, 2025, 44(1): 100381-100381. doi: 10.1016/j.cjsc.2024.100381
10. [10]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
11. [11]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
12. [12]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
13. [13]
  Chang Liu , Zirui Song , Xinglan Deng , Shihong Xu , Renji Zheng , Wentao Deng , Hongshuai Hou , Guoqiang Zou , Xiaobo Ji . Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors. Chinese Chemical Letters, 2024, 35(6): 109081-. doi: 10.1016/j.cclet.2023.109081
14. [14]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
15. [15]
  Zhe Wang , Li-Peng Hou , Qian-Kui Zhang , Nan Yao , Aibing Chen , Jia-Qi Huang , Xue-Qiang Zhang . High-performance localized high-concentration electrolytes by diluent design for long-cycling lithium metal batteries. Chinese Chemical Letters, 2024, 35(4): 108570-. doi: 10.1016/j.cclet.2023.108570
16. [16]
  Jun Jiang , Tong Guo , Wuxin Bai , Mingliang Liu , Shujun Liu , Zhijie Qi , Jingwen Sun , Shugang Pan , Aleksandr L. Vasiliev , Zhiyuan Ma , Xin Wang , Junwu Zhu , Yongsheng Fu . Modularized sulfur storage achieved by 100% space utilization host for high performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(4): 108565-. doi: 10.1016/j.cclet.2023.108565
17. [17]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
18. [18]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
19. [19]
  Yang Deng , Yitao Ouyang , Chao Han . Constriction-susceptible makes fast cycling of lithium metal in solid-state batteries: Silicon as an example. Chinese Journal of Structural Chemistry, 2024, 43(7): 100276-100276. doi: 10.1016/j.cjsc.2024.100276
20. [20]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(584)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of carbon nanotubes addition on electrochemical performance and thermal stability of Li4Ti5O12 anode in commercial LiMn2O4/Li4Ti5O12 full-cell

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of carbon nanotubes addition on electrochemical performance and thermal stability of Li₄Ti₅O₁₂ anode in commercial LiMn₂O₄/Li₄Ti₅O₁₂ full-cell