Citation: Wei-Yi Zhang, Guo-Song Chen. A facile approach to prepare hybrid nanoparticles with morphology controlled by the thickness of glyco-shell[J]. Chinese Chemical Letters, ;2015, 26(7): 847-850. doi: 10.1016/j.cclet.2015.05.022 shu

A facile approach to prepare hybrid nanoparticles with morphology controlled by the thickness of glyco-shell

Wei-Yi Zhang ,
Guo-Song Chen ^,

1.
The State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science, Fudan University, Shanghai 200433, China

Corresponding author: Guo-Song Chen,
Received Date: 1 April 2015
Available Online: 28 April 2015
Fund Project: National Natural Science Foundation of China (No. 91227203, 21474020 and 51322306) (No. 2011CB932503332)

Herein, we designed a novel amphiphilic triblock glycopolymer poly(oligo(ethyleneglycol) methacrylate)- block-poly(maltopyranoside methacrylate)-block-polystyrene (POMA-b-PMal-b-PS) via the combination of reversuble addition-fragmentation chain transfer (RAFT) polymerization and postpolymerization modification. The micelles with core-shell-corona structures were prepared by direct self-assembly of this glycopolymer in water. We found that these micelles can be used in in situ formation and stabilization of AuNPs. By controlling the thickness of glyco-shell, we successfully obtained Janus particles and raspberry-like particles with AuNPs in the sugar shell.
- Glycopolymer,
- Self-assembly,
- Gold nanoparticles,
- Morphology
1. [1]
  [1] A. Ghadban, L. Albertin, Synthesis of glycopolymer architectures by reversibledeactivation radical polymerization, Polymers 5 (2013) 431–526.
2. [2]
  [2] C. Zheng, Q.Q. Guo, Z.M. Wu, et al., Amphiphilic glycopolymer nanoparticles as vehicles for nasal delivery of peptides and proteins, Eur. J. Pharm. Sci. 49 (2013) 474–482.
3. [3]
  [3] A.L. Parry, N.A. Clemson, J. Ellis, et al., ‘Multicopy Multivalent' glycopolymerstabilized gold nanoparticles as potential synthetic cancer vaccines, J. Am. Chem. Soc. 135 (2013) 9362–9365.
4. [4]
  [4] T. Xing, X.Z. Yang, L.Y. Fu, L.F. Yan, Near infrared fluorescence probe and galactose conjugated amphiphilic copolymer for bioimaging of HepG2 cells and endocytosis, Polym. Chem. 4 (2013) 4442–4449.
5. [5]
  [5] M.H. Mashhadizadeh, R.P. Talemi, Application of diazo-thiourea and gold nanoparticles in the design of a highly sensitive and selective DNA biosensor, Chin. Chem. Lett. 26 (2015) 160–166.
6. [6]
  [6] X.H. Lv, L.P. Wang, G. Li, et al., Preparation and characterization of optically functional hollow sphere hybrid materials by surface-initiated RATRP and “click” chemistry, Chin. Chem. Lett. 24 (2013) 335–337.
7. [7]
  [7] M. Takara, M. Toyoshima, H. Seto, Y. Hoshino, Y. Miura, Polymer-modified gold nanoparticles via RAFT polymerization: a detailed study for a biosensing application, Polym. Chem. 5 (2014) 931–939.
8. [8]
  [8] A. Pfaff, A. Schallon, T.M. Ruhland, et al., Magnetic and fluorescent glycopolymer hybrid nanoparticles for intranuclear optical imaging, Biomacromolecules 12 (2011) 3805–3811.
9. [9]
  [9] K. Kuroda, T. Ishida, M. Haruta, Reduction of 4-nitrophenol to 4-aminophenol over Au nanoparticles deposited on PMMA, J. Mol. Catal. A: Chem. 298 (2009) 7–11.
10. [10]
  [10] K. Esumi, T. Hosoya, A. Suzuki, K. Torigoe, Spontaneous formation of gold nanoparticles in aqueous solution of sugar-persubstituted poly(amidoamine) dendrimers, Langmuir 16 (2000) 2978–2980.
11. [11]
  [11] L. Su, C.M. Wang, F. Polzer, et al., Glyco-inside micelles and vesicles directed by protection–deprotection chemistry, ACS Macro Lett. 3 (2014) 534–539.
12. [12]
  [12] Y.X. Zhang, X.D. Hao, Z.P. Diao, Templated self-assembly of Au–TiO₂ binary nanoparticles–nanotubes, Chin. Chem. Lett. 25 (2014) 874–878.
13. [13]
  [13] T. Chen, M.X. Yang, X.J. Wang, L.H. Tan, H.Y. Chen, Controlled assembly of eccentrically encapsulated gold nanoparticles, J. Am. Chem. Soc. 130 (2008) 11858–11859.
14. [14]
  [14] J. He, M.T. Perez, P. Zhang, et al., A general approach to synthesize asymmetric hybrid nanoparticles by interfacial reactions, J. Am. Chem. Soc. 134 (2012) 3639– 3642.
15. [15]
  [15] W.P. Li, V. Shanmugam, C.C. Huang, et al., Eccentric inorganic-polymeric nanoparticles formation by thermal induced cross-linked esterification and conversion of eccentricity to raspberry-like Janus, Chem. Commun. 49 (2013) 1609–1611.
16. [16]
  [16] N. Ali, S.Y. Park, Micellar structures of poly(styrene-b-4-vinylpyridine)s in THF/ Toluene mixtures and their functionalization with gold, Langmuir 24 (2008) 9279–9285.
17. [17]
  [17] T. Premkumar, K. Lee, K.E. Geckeler, Shape-tailoring of gold nanostructures: can a detergent act as the reducing or protecting agent? Nanoscale 3 (2011) 1482– 1484.
18. [18]
  [18] R. Fenger, E. Fertitta, H. Kirmse, A.F. Thü nemann, K. Rademann, Size dependent catalysis with CTAB-stabilized gold nanoparticles, Phys. Chem. Chem. Phys. 14 (2012) 9343–9349.
19. [19]
  [19] Y.Wang, G.W.Wei, W.Q. Zhang, et al., Responsive catalysis of thermoresponsive micelle-supported gold nanoparticles, J. Mol. Catal. A: Chem. 266 (2007) 233–238.
1. [1]
  Jiaye Wang , Xiong Yang , Yang Lei , Tianwen Xi , Sijie Wang , Yidan Zhou , Bing Liu , Yu Liu , Hui Yang , Leming Sun . Zinc coordination self-assembly of bacitracin nanoparticles with broadened antibacterial spectrum. Chinese Chemical Letters, 2026, 37(4): 111086-. doi: 10.1016/j.cclet.2025.111086
2. [2]
  Hao Zhang , Hao Liu , Ke Huang , Qingxiu Xia , Hongjie Xiong , Xiaohui Liu , Hui Jiang , Xuemei Wang . Ionic exchange based intracellular self-assembly of pitaya-structured nanoparticles for tumor imaging. Chinese Chemical Letters, 2025, 36(6): 110281-. doi: 10.1016/j.cclet.2024.110281
3. [3]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
4. [4]
  Shengxia Yang , Yukang Pan , Tianyu Kong , Chaoran Jia , Yueyang Cui , Xuehua Li , Yannan Zhou , Haijun Liu , Xinyu Zhang , Bin Dong , Qunwei Tang . Ru and S co-modification-induced synergistic morphology and electronic engineering of nickel-iron hydroxide with efficient oxygen evolution. Chinese Chemical Letters, 2025, 36(12): 111540-. doi: 10.1016/j.cclet.2025.111540
5. [5]
  Xiangqian Cao , Chenkai Yang , Xiaodong Zhu , Mengxin Zhao , Yilin Yan , Zhengnan Huang , Jinming Cai , Jingming Zhuang , Shengzhou Li , Wei Li , Bing Shen . Synergistic enhancement of chemotherapy for bladder cancer by photothermal dual-sensitive nanosystem with gold nanoparticles and PNIPAM. Chinese Chemical Letters, 2024, 35(8): 109199-. doi: 10.1016/j.cclet.2023.109199
6. [6]
  Yuanpeng Ye , Longfei Yao , Guofeng Liu . Engineering circularly polarized luminescence through symmetry manipulation in achiral tetraphenylpyrazine structures. Chinese Journal of Structural Chemistry, 2025, 44(2): 100460-100460. doi: 10.1016/j.cjsc.2024.100460
7. [7]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
8. [8]
  Yiyang Shen , Zhen Zhang , Ruyi Liang , Tongbo Wu . Unraveling the interplay of DNAzyme and interfacial factors for enhanced biosensing. Chinese Chemical Letters, 2024, 35(12): 109638-. doi: 10.1016/j.cclet.2024.109638
9. [9]
  Ze Cao , Chenqi Ge , Yating Wu , Hua Tang , Yueyan Kuang , Yuyang Wu , Hao Li . Self-assembled chiral cages for anion recognition. Chinese Chemical Letters, 2026, 37(3): 111554-. doi: 10.1016/j.cclet.2025.111554
10. [10]
  Shengyong Liu , Hui Li , Wei Zhang , Yan Zhang , Yan Dong , Wei Tian . Multiple host-guest and metal coordination interactions induce supramolecular assembly and structural transition. Chinese Chemical Letters, 2025, 36(6): 110465-. doi: 10.1016/j.cclet.2024.110465
11. [11]
  Jingqi Xin , Shupeng Han , Meichen Zheng , Chenfeng Xu , Zhongxi Huang , Bin Wang , Changmin Yu , Feifei An , Yu Ren . A nitroreductase-responsive nanoprobe with homogeneous composition and high loading for preoperative non-invasive tumor imaging and intraoperative guidance. Chinese Chemical Letters, 2024, 35(7): 109165-. doi: 10.1016/j.cclet.2023.109165
12. [12]
  Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
13. [13]
  Xuanyu Wang , Zhao Gao , Wei Tian . Supramolecular confinement effect enabling light-harvesting system for photocatalytic α-oxyamination reaction. Chinese Chemical Letters, 2024, 35(11): 109757-. doi: 10.1016/j.cclet.2024.109757
14. [14]
  Xian Yan , Huawei Xie , Gao Wu , Fang-Xing Xiao . Boosted solar water oxidation steered by atomically precise alloy nanocluster. Chinese Chemical Letters, 2025, 36(1): 110279-. doi: 10.1016/j.cclet.2024.110279
15. [15]
  Feng Cao , Chunxiang Xian , Tianqi Yang , Yue Zhang , Haifeng Chen , Xinping He , Xukun Qian , Shenghui Shen , Yang Xia , Wenkui Zhang , Xinhui Xia . Gelation-pyrolysis strategy for fabrication of advanced carbon/sulfur cathodes for lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 110575-. doi: 10.1016/j.cclet.2024.110575
16. [16]
  Fengying Ye , Ming Hu , Jun Luo , Wei Yu , Zhirong Xu , Jinjin Fu , Yansong Zheng . Significantly boosting circularly polarized luminescence by synergy of helical and planar chirality. Chinese Chemical Letters, 2025, 36(5): 110724-. doi: 10.1016/j.cclet.2024.110724
17. [17]
  Weibin Shen , Jie Liu , Gongyu Wen , Shuai Li , Binhui Yu , Shuangyu Song , Bojie Gong , Rongyang Zhang , Shibao Liu , Hongpeng Wang , Yao Wang , Yujing Liu , Huadong Yuan , Jianming Luo , Shihui Zou , Xinyong Tao , Jianwei Nai . Formation of FeNi-based nanowire-assembled superstructures with tunable anions for electrocatalytic oxygen evolution reaction. Chinese Chemical Letters, 2025, 36(7): 110184-. doi: 10.1016/j.cclet.2024.110184
18. [18]
  Xingyue Yuan , Li Wu , Qiuyu Peng , Yanyan Tang , Mingxu Wang , Yuhang Wei , Zhu Tao , Xin Xiao . Developing color-tunable long afterglow anti-counterfeiting materials using cucurbit[6]uril and classical aggregation-caused quenching compounds through multiple non-covalent interactions. Chinese Chemical Letters, 2025, 36(9): 110821-. doi: 10.1016/j.cclet.2025.110821
19. [19]
  Shuwen Guo , Haipeng Xu , Zijun Cheng , Leyong Wang , Peng Yang , Ruibing Wang . Efficient cytosolic delivery of protein by preorganized amidiniums on pillar[5]arene. Chinese Chemical Letters, 2025, 36(10): 111022-. doi: 10.1016/j.cclet.2025.111022
20. [20]
  Qunpeng Duan , Qiaona Zhang , Jiayuan Zhang , Shihao Lin , Tangxin Xiao , Leyong Wang . Artificial light-harvesting systems based on supramolecular polymers ^✩. Chinese Chemical Letters, 2025, 36(12): 111421-. doi: 10.1016/j.cclet.2025.111421

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1282)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142