Citation: Feng Yu, Ming-Yuan Zhu, Fei-Hong Ouyang, Bin Dai, Jian-Ming Dan. Hydrochlorination of acetylene using expanded multilayered vermiculite (EML-VMT)-supported catalysts[J]. Chinese Chemical Letters, ;2015, 26(9): 1101-1104. doi: 10.1016/j.cclet.2015.05.020 shu

Hydrochlorination of acetylene using expanded multilayered vermiculite (EML-VMT)-supported catalysts

¹ ,
Feng Yu ^1,2,3,, ,
Ming-Yuan Zhu ¹ ,
Fei-Hong Ouyang ¹ ,
Bin Dai ¹ ,
Jian-Ming Dan ^1,2,3,,

1.
1 Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, China;
2.
2 Engineering Research Center of Materials-Oriented Chemical Engineering of Xinjiang Production and Construction Corps, Shihezi 832003, China;
3.
3 Key Laboratory of Materials-Oriented Chemical Engineering of Xinjiang Uygur Autonomous Region, Shihezi 832003, China

Corresponding author: Feng Yu, Jian-Ming Dan,
Received Date: 27 March 2015
Available Online: 5 May 2015
Fund Project: This work was financially supported by National Natural Science Foundation of China (Nos. 21163015, 21366027) (Nos. 21163015, 21366027) the Doctor Foundation of Bingtuan (No. 2014BB004) (No. 2014BB004) the National Basic Research Program of China (973Program, No. 2012CB720300) (973Program, No. 2012CB720300) the Program for Changjiang Scholars, Innovative Research Team in University (No. IRT1161) (No. IRT1161)

Catalyst supports have very important effects on catalyst performance. A novel expanded multilayered vermiculite (EML-VMT) is successfully used as the catalyst support for the acetylene hydrochlorination. By mixing carbon on the surface of EML-VMT (i.e., EML-VMT-C), the HgCl₂/EML-VMT-C achieved a high acetylene conversion of 97.3%, a vinyl chloride selectivity of 100% and a turn over frequency (TOF) value of 8.83×10^-3 s^-1 at a temperature of 140℃, an acetylene gas hourly space velocity (GHSV) of 108 h^-1, and a feed volume ratio V(HCl)/V(C₂H₂) of 1.15. Moreover, the HgCl₂/EML-VMT-C shows good stability. The EML-VMT also shows potential in the preparation of other EML-VMT-supported catalysts.
- Acetylene hydrochlorination,
- Vermiculite,
- Catalyst support,
- Acetylene conversion,
- Vinyl chloride selectivity
1. [1]
  [1] X.Y. Li, M.Y. Zhu, B. Dai, AuCl₃ on polypyrrole-modified carbon nanotubes as acetylene hydrochlorination catalysts, Appl. Catal. B:Environ. 142-143(2013) 234-240.
2. [2]
  [2] J.L. Zhang, N. Liu, W. Li, B. Dai, Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts, Front. Chem. Sci. Eng. 5(2011) 514-520.
3. [3]
  [3] K. Zhou, B. Li, Q. Zhang, et al., The catalytic pathways of hydrohalogenation over metal-free nitrogen-doped carbon nanotubes, ChemSusChem 7(2014) 723-728.
4. [4]
  [4] K. Zhou, J.C. Jia, X.G. Li, et al., Continuous vinyl chloride monomer production by acetylene hydrochlorination on Hg-free bismuth catalyst:from lab-scale catalyst characterization, catalytic evaluation to a pilot-scale trial by circulating regeneration in coupled fluidized beds, Fuel Process. Technol. 108(2013) 12-18.
5. [5]
  [5] H. Bremer, H. Lieske, Kinetics of the hydrochlorination of acetylene on HgCl₂/active carbon catalysts, Appl. Catal. 18(1985) 191-203.
6. [6]
  [6] C.Y. Hou, L.R. Feng, F.L. Qiu, Highly active catalyst for vinyl acetate synthesis by modified activated carbon, Chin. Chem. Lett. 20(2009) 865-868.
7. [7]
  [7] X.Y. Li, X.L. Pan, X.H. Bao, Nitrogen doped carbon catalyzing acetylene conversion to vinyl chloride, J. Energy Chem. 23(2014) 131-135.
8. [8]
  [8] J.H. Xu, J. Zhao, J.T. Xu, et al., Influence of surface chemistry of activated carbon on the activity of gold/activated carbon catalyst in acetylene hydrochlorination, Ind. Eng. Chem. Res. 53(2014) 14272-14281.
9. [9]
  [9] K. Zhou, J.C. Jia, C.H. Li, et al., A low content Au-based catalyst for hydrochlorination of C₂H₂ and its industrial scale-up for future PVC processes, Green Chem. 17(2015) 356-364.
10. [10]
  [10] K. Zhou, J.K. Si, J.C. Jia, et al., Reactivity enhancement of N-CNTs in green catalysis of C₂H₂ hydrochlorination by a Cu catalyst, RSC Adv. 4(2014) 7766-7769.
11. [11]
  [11] X.Y. Li, X.L. Pan, L. Yu, et al., Silicon carbide-derived carbon nanocomposite as a substitute for mercury in the catalytic hydrochlorination of acetylene, Nat. Commun. 5(2014) 3688.
12. [12]
  [12] J. Zhang, T.Y. Liu, R. Chen, X.H. Liu, Vermiculite as a natural silicate crystal for hydrogen generation from photocatalytic splitting of water under visible light, RSC Adv. 4(2014) 406-408.
13. [13]
  [13] F.H. do Nascimento, J.C. Masini, Influence of humic acid on adsorption of Hg(II) by vermiculite, J. Environ. Manag. 143(2014) 1-7.
14. [14]
  [14] Y.F. Liu, Z.H. He, L. Zhou, Z.S. Hou, W.M.J. Eli, Simultaneous oxidative conversion and CO₂ reforming of methane to syngas over Ni/vermiculite catalysts, Catal. Commun. 42(2013) 40-44.
15. [15]
  [15] L.C.R. Machado, C.B. Torchia, R.M. Lago, Floating photocatalysts based on TiO₂ supported on high surface area exfoliated vermiculite for water decontamination, Catal. Commun. 7(2006) 538-541.
16. [16]
  [16] Y. Sun, L. Liu, D.Z. Jia, J.H. Liu, Preparation and properties of vermiculite supported TiO₂ photocatalyst, Chin. J. Inorg. Chem. 27(2011) 40-46.
17. [17]
  [17] X.G. Wang, B. Dai, Y. Wang, F. Yu, Nitrogen-doped pitch-based spherical active carbon as a nonmetal catalyst for acetylene hydrochlorination, ChemCatChem 6(2014) 2339-2344.
18. [18]
  [18] H.Y. Zhang, B. Dai, W. Li, et al., Non-mercury catalytic acetylene hydrochlorination over spherical activated-carbon-supported Au-Co (III)-Cu (II) catalysts, J. Catal. 316(2014) 141-148.
19. [19]
  [19] M.Y. Zhu, L.H. Kang, Y. Su, S.Z. Zhang, B. Dai, MCl_x (M=Hg, Au, Ru; x=2, 3) catalyzed hydrochlorination of acetylene-A density functional theory study, Can. J. Chem. 91(2013) 120-125.
20. [20]
  [20] F. Yu, L.L. Zhang, M.Y. Zhu, et al., Overwhelming microwave irradiation assisted synthesis of olivine-structured LiMPO₄(M=Fe, Mn, Co and Ni) for Li-ion batteries, Nano Energy 3(2014) 64-79.
21. [21]
  [21] F. Yu, S.H. Lim, Y.D. Zhen, Y.X. An, J.Y. Lin, Optimized electrochemical performance of three-dimensional porous LiFePO₄/C microspheres via microwave irradiation assisted synthesis, J. Power Sources 271(2014) 223-230.
22. [22]
  [22] Y.-H. Ma, G. Wu, N. Jiang, et al., Microwave-assisted, facile, rapid and solvent-free one pot two-component synthesis of some special acylals, Chin. Chem. Lett. 26(2015) 81-84.
23. [23]
  [23] S. Ittu, N. Constantin, Some characteristics of vermiculite mineral, Metal. Int. 18(2013) 73-76.
24. [24]
  [24] S. Hillier, E.M.M. Marwa, C.M. Rice, On the mechanism of exfoliation of 'Vermiculite', Clay Miner. 48(2013) 563-582.
25. [25]
  [25] X.X. Huo, L.M. Wu, L.B. Liao, Z.G. Xia, L.J. Wang, The effect of interlayer cations on the expansion of vermiculite, Powder Technol. 224(2012) 241-246.
26. [26]
  [26] L.L. Xu, X.G. Wang, H.Y. Zhang, et al., Application of a novel carbon carrier in acetylene hydrochlorination, Chem. Ind. Eng. Prog. 30(2011) 536-541.
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