Citation: Kui Gao, Xu-Heng Jiang, Dao-Pan Hu, Shu-Juan Bian, Meng Wang, Yong Chen. Impact of an ionic surfactant on the ion transfer behaviors at meso-liquid/liquid interface arrays[J]. Chinese Chemical Letters, ;2015, 26(3): 285-288. doi: 10.1016/j.cclet.2014.12.003 shu

Impact of an ionic surfactant on the ion transfer behaviors at meso-liquid/liquid interface arrays

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School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

Corresponding author: Yong Chen,
Received Date: 1 September 2014
Available Online: 2 November 2014
Fund Project: This work was supported by the National Science Foundation of China (No. 21005049) (No. 21005049)the Natural Science Foundation of Shanghai, China (No. 14ZR1440900). (No. 14ZR1440900)

The influence of ionic surfactants, cetyltrimethylammonium bromide (CTAB), self-assembled within silica-nanochannels of a hybrid mesoporous silica membrane (HMSM) on simple ion transfer (IT) behaviors at the meso-water/1,2-dichloroethane (W/DCE) interface arrays supported by such a HMSM was investigated by voltammetry for the first time. Significantly, it is found that the CTAB in HMSM can dramatically enhance the peak-current responses corresponding to ITs of some anions and even lower their Gibbs transfer energies from W to DCE, which could be ascribed to an anion-exchange process between anions and the bromide of CTAB associated with partial ion-dehydration induced by the CTAB. This work will provide a new strategy to study anion transfer processes and improve the electroanalytical performance for anion detection at the liquid/liquid interface.
- Mesoporous membrane,
- Surfactant,
- Liquid/liquid interface,
- Ion transfer,
- Voltammetry
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沈阳化工大学材料科学与工程学院沈阳 110142