Citation: Wen-Jie Wu, Hong-Xiang Huang, Meng Chen, Dong-Jin Qian. Synthesis and luminescent properties of a silylated-terpyridine derivative and its metalated complexes in solutions and self-assembled monolayers[J]. Chinese Chemical Letters, ;2015, 26(3): 343-347. doi: 10.1016/j.cclet.2014.11.025 shu

Synthesis and luminescent properties of a silylated-terpyridine derivative and its metalated complexes in solutions and self-assembled monolayers

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a Department of Chemistry, Fudan University, Shanghai 200433, China;
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b State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200433, China

Corresponding author: Dong-Jin Qian,
Received Date: 13 August 2014
Available Online: 13 November 2014
Fund Project: This work was supported by National Natural Science Foundation of China (No. 21373058) (No. 21373058)

A silylated-terpyridine (SiTPy) derivative was newly synthesized and reacted with various transition metal ions in the solutions and self-assembled monolayers (SAMs). Composition and morphology of the SAMs were characterized by using absorption spectra, X-ray photoelectron spectra and atomic force microscope. The silylated-TPy compound gave off a luminescent emission at about 456 nm, which slightly shifted to 452 nm in the Zn²⁺-SiTPy and Fe²⁺-SiTPy metalated complexes. The absorbed energy can be further transferred to lanthanide ions (Tb³⁺ and Eu³⁺) to give off the typical emissions of the lanthanide complexes together with an emission of the silylated-TPy at about 363 nm.
- Silylated-terpyridine,
- Metal complexes,
- Self-assembled monolayer,
- Fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142