Citation: Hao Wang, Yi-Ping Chen, Zhu-Chai You, Meng-Xi Zhou, Ning Zhang, Yan-Qiong Sun. Synthesis and characterization of a new catalyst for RhB degradation constructed by [SiMo₁₂O₄₀]^4- anionic cluster[J]. Chinese Chemical Letters, ;2015, 26(2): 187-192. doi: 10.1016/j.cclet.2014.11.023 shu

Synthesis and characterization of a new catalyst for RhB degradation constructed by [SiMo₁₂O₄₀]^4- anionic cluster

1.
a College of Chemistry, Fuzhou University, Fuzhou 350108, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Yi-Ping Chen,
Received Date: 21 July 2014
Available Online: 29 September 2014
Fund Project: This research was financially supported by the National Science Foundation of China (Nos. 21473030, J1103303) (Nos. 21473030, J1103303) Fujian Provincial Natural Science Foundation (No. 2013J01042) (No. 2013J01042) Open Fund of State Key Laboratory of Structural Chemistry (No. 20130015) (No. 20130015)

A Keggin-type polyoxomolybdate [H₂biim]{Ni(biim)₃(SiMo₁₂O₄₀)} [biim=1H,1'H-[2,2']biimidazolyl] has been synthesized under hydrothermal condition and characterized by XRD, temperature-dependent IR, TG, temperature-induced and magnetism-induced 2D infrared correlation spectroscopy (2D-IR COS) and UV-vis DRS in order to explore the relationship between structure and properties. Temperatureinduced 2D-IR COS spectroscopy indicates that the terminal Mo-O_u/v bonds are more sensitive than the bridging Mo=O_t bands to temperature variation, which is in agreement with the conclusion of temperature-dependent IR. Magnetism-dependent 2D-IR COS spectroscopy reveals the stretching vibration of the Mo=O_t occurs prior to the stretching vibration of the Mo-O_u/v, which is due to the coordination environment and the valence of the Siatom. The stability of compound 1 is investigated via TG and temperature-dependent IR. In RhB degradation, compound 1 shows good photocatalytic abilities.
- 2D infrared correlation spectroscopy,
- Photocatalytic degradation of RhB,
- Silicon molybdenum polyoxometalate
1. [1]
  [1] K. Ulrich, V. Jacqueline, T. Ren, et al., Heteropolymolybdates of phosphate, phosphonate, and phosphite functionalized by glycine, Inorg. Chem. 42 (2003) 1135-1139.
2. [2]
  [2] J.R.G. Mascaros, M.G. Carlos, Supramolecular stabilization of the phosphitebased polyoxomolybdate [Mo₆(PO₃)(HPO₃)₃O₁₈]^-9, Polyhedron 26 (2007) 626-630.
3. [3]
  [3] C.H. Li, Q. Wang, Y.N. Chi, et al., Supramolecular assembly of Keggin polyoxomolybdate and 2,2-bipyridine generated in situ from a decarboxylation coupling reaction, Chin. Chem. Lett. 24 (2013) 578-580.
4. [4]
  [4] T. Safa, A. Brahim, H. Amor, A novel organic-inorganic hybrid with Anderson type polyanions as building blocks: (C6H10N3O2)2Na(H₂O)2[Al(OH)₆Mo₆O₁₈] 6H₂O, Mater. Res. Bull. 47 (2012) 3791-3796.
5. [5]
  [5] H.Y. Lü, W.Z. Ren, W.P. Liao, et al., Aerobic oxidative desulfurization of model diesel using a B-type Anderson catalyst [(C₁₈H₃₇)₂N(CH₃)₂]3Co(OH)6Mo6O18 3H₂O, Appl. Catal. B: Environ. 138-139 (2013) 79-83.
6. [6]
  [6] H.Q. Tan, Y.G. Li, W.L. Chen, et al., A series of [MnMo₉O₃₂]6 based solids: homochiral transferred from adjacent polyoxoanions to one-, two-, and threedimensional frameworks, Cryst. Growth Des. 12 (2012) 1111-1117.
7. [7]
  [7] C.D. Wu, C.Z. Lu, H.H. Zhuang, et al., Hydrothermal assembly of a novel threedimensional framework formed by [GdMo12O42]9 anions and nine coordinated GdIII cations, J. Am. Chem. Soc. 124 (2002) 3836-3837.
8. [8]
  [8] M. Sarma, T. Chatterjee, H. Vindhya, et al., Spontaneous resolution through helical association of a Cu-azamacrocyclic complex with Lindqvist-type isopolyanion, Dalton Trans. 41 (2012) 1862-1866.
9. [9]
  [9] R.N. Devi, J. Zubieta, Synthesis and characterization of three novel inorganic/ organic hybrid materials based on polyoxomolybdate clusters: an investigation into the structural consequences of steric effect of the organoimine ligands, Inorg. Chim. Acta 332 (2002) 72-78.
10. [10]
  [10] Y.B. Huang, J.X. Chen, T.Y. Lan, et al., Syntheses, structures and properties of two Keggin polyoxometalates [H5PCo(4,40-bipy)Mo11O39][H₃PMo₁₂O₄₀] 3.75 (4,40-bipy) 1.5H₂O and [H₃PMo₁₂O₄₀] 2(4,40-bipy) 1.5H₂O, J. Mol. Struct. 783 (2006) 168-175.
11. [11]
  [11] Y.P. Shi, W. Yang, G.L. Xue, et al., A novel crystal coexisting with two kinds of polyoxomolybdates: [n-Bu4N]8[Mo6O19]2[a-(Mo8O26)], J. Mol. Struct. 784 (2006) 244-248.
12. [12]
  [12] N. Sonoyama, Y. Suganuma, T. Kume, et al., Lithium intercalation reaction into the Keggin type polyoxomolybdates, J. Power Sources 196 (2011) 6822-6827.
13. [13]
  [13] K. Yu, B.B. Zhou, Y. Yu, et al., Supramolecular assembly based on Keggin cluster and basketlike cage, Inorg. Chem. Commun. 14 (2011) 1846-1849.
14. [14]
  [14] Y.R. Guo, Q.J. Pan, Y.D. Wei, et al., Theoretical studies on the electronic and spectroscopic properties of Keggin-structure polyoxometalates a/b-[XM₁₂O₄₀]n (X=Si, P; M=Mo, W), J. Mol. Struct.: THEOCHEM 676 (2004) 55-64.
15. [15]
  [15] N. Ronny, L. Michal, Aerobic oxidative dehydrogenations catalyzed by the mixedaddenda heteropolyanion PV₂Mo₁₀O₄₀^-5: a kinetic and mechanistic study, J. Am. Chem. Soc. 114 (1992) 7278-7286.
16. [16]
  [16] L. Manfred, J. Helmut, Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion, Tetrahedron Lett. 33 (1992) 1795-1798.
17. [17]
  [17] S.L. Linguito, X. Zhang, M. Padmanabhan, et al., New polyoxomolybdate compounds synthesized in situ using ionic liquid 1-butyl-3-methyl-imidazolium tetrafluoroborate as green solvent, New J. Chem. 37 (2013) 2894-2901.
18. [18]
  [18] I. Noda, Two-dimensional infrared spectroscopy, J. Am. Chem. Soc. 111 (1989) 8116-8118.
19. [19]
  [19] I. Noda, Progress in two-dimensional (2D) correlation spectroscopy, J. Mol. Struct. 799 (2006) 2-15.
20. [20]
  [20] I. Noda, Two-dimensional correlation spectroscopy-biannual survey 2007-2009, J. Mol. Struct. 974 (2010) 3-24.
21. [21]
  [21] Y.N. Cao, H.H. Zhang, C.C. Huang, et al., Synthesis, crystal structure and twodimensional infrared correlation spectroscopy of a layer-like transition metal (TM)-oxalate templated polyoxovanadium borate, J. Solid State Chem. 178 (2005) 3563-3570.
22. [22]
  [22] (a) G.M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution, University of GÖ ttingen, Germany, 1997; (b) G.M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, University of GÖ ttingen, Germany, 1997.
23. [23]
  [23] J. Chen, J.Q. Sha, J. Peng, et al., Self-assembly of two novel bisupporting Kegginpolyoxometalate derivatives: hydrothermal synthesis and structure characterization of [Cu(2,20-bpy)₂]₂[HmXMo₁₀Mo₂O₄₀] 2H₂O (X=P, m=1; X=Si, m=2), J. Mol. Struct. 846 (2007) 128-133.
24. [24]
  [24] X.Y. Yu, X.B. Cui, J. Lu, et al., Five inorganic-organic hybrids based on Keggin polyanion [SiMo₁₂O₄₀]^4-: from 0D to 2D network, J. Solid State Chem. 209 (2014) 97-104.
25. [25]
  [25] X.Y. Chen, Y.P. Chen, Z. Xia, et al., Synthesis, crystal structure of a-Keggin heteropolymolybdates with pyridine-2,6-dicarboxylate based frameworks, and associated RhB photocatalytic degradation and 2D-IR COS tests, Dalton Trans. 41 (2012) 10035-10042.
26. [26]
  [26] X.L. Hao, Y.Y. Ma, Y.H. Wang, et al., New organic-inorganic hybrid assemblies based on metal-bis(betaine) coordination complexes and Keggin-type polyoxometalates, Inorg. Chem. Commun. 41 (2014) 19-24.
1. [1]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
2. [2]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
3. [3]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
4. [4]
  Zhi Zhu , Xiaohan Xing , Qi Qi , Wenjing Shen , Hongyue Wu , Dongyi Li , Binrong Li , Jialin Liang , Xu Tang , Jun Zhao , Hongping Li , Pengwei Huo . Fabrication of graphene modified CeO2/g-C3N4 heterostructures for photocatalytic degradation of organic pollutants. Chinese Journal of Structural Chemistry, 2023, 42(12): 100194-100194. doi: 10.1016/j.cjsc.2023.100194
5. [5]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
6. [6]
  Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
7. [7]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
8. [8]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
9. [9]
  Chaozheng He , Jia Wang , Ling Fu , Wei Wei . Nitric oxide assists nitrogen reduction reaction on 2D MBene: A theoretical study. Chinese Chemical Letters, 2024, 35(5): 109037-. doi: 10.1016/j.cclet.2023.109037
10. [10]
  Jaeyong Ahn , Zhenping Li , Zhiwei Wang , Ke Gao , Huagui Zhuo , Wanuk Choi , Gang Chang , Xiaobo Shang , Joon Hak Oh . Surface doping effect on the optoelectronic performance of 2D organic crystals based on cyano-substituted perylene diimides. Chinese Chemical Letters, 2024, 35(9): 109777-. doi: 10.1016/j.cclet.2024.109777
11. [11]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
12. [12]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
13. [13]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
14. [14]
  Shenghui Tu , Anru Liu , Hongxiang Zhang , Lu Sun , Minghui Luo , Shan Huang , Ting Huang , Honggen Peng . Oxygen vacancy regulating transition mode of MIL-125 to facilitate singlet oxygen generation for photocatalytic degradation of antibiotics. Chinese Chemical Letters, 2024, 35(12): 109761-. doi: 10.1016/j.cclet.2024.109761
15. [15]
  Manyu Zhu , Fei Liang , Lie Wu , Zihao Li , Chen Wang , Shule Liu , Xiue Jiang . Revealing the difference of Stark tuning rate between interface and bulk by surface-enhanced infrared absorption spectroscopy. Chinese Chemical Letters, 2025, 36(2): 109962-. doi: 10.1016/j.cclet.2024.109962
16. [16]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
17. [17]
  Xingyan Liu , Chaogang Jia , Guangmei Jiang , Chenghua Zhang , Mingzuo Chen , Xiaofei Zhao , Xiaocheng Zhang , Min Fu , Siqi Li , Jie Wu , Yiming Jia , Youzhou He . Single-atom Pd anchored in the porphyrin-center of ultrathin 2D-MOFs as the active center to enhance photocatalytic hydrogen-evolution and NO-removal. Chinese Chemical Letters, 2024, 35(9): 109455-. doi: 10.1016/j.cclet.2023.109455
18. [18]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
19. [19]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
20. [20]
  Jieqiong Qin , Zhi Yang , Jiaxin Ma , Liangzhu Zhang , Feifei Xing , Hongtao Zhang , Shuxia Tian , Shuanghao Zheng , Zhong-Shuai Wu . Interfacial assembly of 2D polydopamine/graphene heterostructures with well-defined mesopore and tunable thickness for high-energy planar micro-supercapacitors. Chinese Chemical Letters, 2024, 35(7): 108845-. doi: 10.1016/j.cclet.2023.108845

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(564)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and characterization of a new catalyst for RhB degradation constructed by [SiMo12O40]4- anionic cluster

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and characterization of a new catalyst for RhB degradation constructed by [SiMo₁₂O₄₀]^4- anionic cluster