Citation: Wen-Yuan Tang, Jing-Jing Guo, Xing-Xing Gui, De-Man Han, Jian-Jun Li. An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction[J]. Chinese Chemical Letters, ;2015, 26(1): 85-88. doi: 10.1016/j.cclet.2014.10.015 shu

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction

1.
a College of Pharmaceutical and Chemical Engineering, Taizhou University, Zhejiang 317000, China;
2.
b Key Laboratory for Green Pharmaceutical Technologies and Related Equipment of Ministry of Education, College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: Jian-Jun Li,
Received Date: 8 July 2014
Available Online: 9 October 2014
Fund Project: We are grateful to the Natural Science Foundation of Zhejiang Province (No. LY13B020015) (No. LY13B020015)

A ring-opening process of 4-imino-1,3-thiazetidin-2-ones with NH₂OH·HCl was described for the first time. Two different scaffolds of imidodicarbonic diamide were obtained selectively in good yields in the presence of organic base. The obtained imidodicarbonic diamides were demonstrated by X-ray diffraction analysis.
- Imidodicarbonic diamides,
- 1,3-Thiazetidin-2-one,
- Hydroxylamine hydrochloride,
- Ring-opening
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An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH2OH·HCl via ring-opening reaction

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通讯作者: 陈斌, bchen63@163.com

An efficient synthesis of imidodicarbonic diamides from 1,3-thiazetidin-2-ones with NH₂OH·HCl via ring-opening reaction