Citation: Fang-Fang Wang, Cheng Chen, Yi Zhang, Da-Wei Fu. Crystal structure and dielectric property of supramolecular macrocyclic [(NDPA)·(18-crown-6)]²⁺·(DMA)⁺·3ClO₄^- assemblies[J]. Chinese Chemical Letters, ;2015, 26(1): 31-35. doi: 10.1016/j.cclet.2014.10.005 shu

Crystal structure and dielectric property of supramolecular macrocyclic [(NDPA)·(18-crown-6)]²⁺·(DMA)⁺·3ClO₄^- assemblies

1.
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, China

Corresponding author: Da-Wei Fu,
Received Date: 25 August 2014
Available Online: 24 September 2014
Fund Project: This work was financially supported by the 973 Project (No. 2014CB848800) (No. 2014CB848800)

One novel organic-inorganic hybrid supramolecular assemblies [(NDPA)·(18-crown-6)]²⁺·(DMA)⁺·3ClO₄^- (1), has been successfully constructed through the prominent strategies of crystal engineering (NDPA = N,N-dimethyl-1,4-phenylenediamine, DMA = dimethylamine), and characterized by IR, powder XRD and single crystal X-ray diffraction. In the structure, the supramolecular organic cations and inorganic ClO₄^- anions are arranged alternately and linked by N-O···H hydrogen bonds. It is worthy to note that the ClO₄^- are linked to form one-dimensional inorganic chain through strong N- H···O hydrogen bonds along b-axis. There is no distinct dielectric anomaly in the temperaturedependent and frequency-dependent dielectric constant curves, suggesting that no phase transition exists within the measured temperature range (120-420 K). The relative displacement of cations and anions, the turned polarization of molecular electric moment and macrocyclic molecule rotator are the main factors to determine the trend of dielectric constant.
- Organic-inorganic hybrid,
- Dielectric constant,
- Macrocyclic assembly,
- Crystal structure
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Crystal structure and dielectric property of supramolecular macrocyclic [(NDPA)·(18-crown-6)]2+·(DMA)+·3ClO4- assemblies

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Crystal structure and dielectric property of supramolecular macrocyclic [(NDPA)·(18-crown-6)]²⁺·(DMA)⁺·3ClO₄^- assemblies