Citation: Yong Na, Bo Hu, Qiu-Ling Yang, Jian Liu, Li Zhou, Rui-Qing Fan, Yu-Lin Yang. CdS quantum dot sensitized p-type NiO as photocathode with integrated cobaloxime in photoelectrochemical cell for water splitting[J]. Chinese Chemical Letters, ;2015, 26(1): 141-144. doi: 10.1016/j.cclet.2014.09.011 shu

CdS quantum dot sensitized p-type NiO as photocathode with integrated cobaloxime in photoelectrochemical cell for water splitting

Yong Na ^a,, ,
Bo Hu ^a ,
Qiu-Ling Yang ^a ,
Jian Liu ^b ,
Li Zhou ^a ,
Rui-Qing Fan ^a ,
Yu-Lin Yang ^a,,

1.
a Department of Chemistry, Harbin Institute of Technology, Harbin 150001, China;
2.
b Center of Ultra-Precision Optoelectronic Instrument Engineering, Harbin Institute of Technology, Harbin 150001, China

Corresponding author: Yong Na, Yu-Lin Yang,
Received Date: 1 June 2014
Available Online: 29 August 2014
Fund Project: This work is supported by the Fundamental Research Funds for the Central Universities (No. HIT. IBRSEM. A. 201409) (No. HIT. IBRSEM. A. 201409) the Program for Innovation Research of Science in Harbin Institute of Technology (PIRS of HIT No. A201418, A201416) (PIRS of HIT No. A201418, A201416)

CdS sensitized NiO electrode was used as the photoactive cathode in a photoelectrochemical cell for water splitting, avoiding the use of a sacrificial electron donor. Photocurrent increment under visible light irradiation was observed after integration of [Co(dmgH)₂(4-Me-py)Cl] (1) to the photocathode, suggesting 1 could accept electrons from photoexcited CdS for water reduction and NiO could move the holes in the valence band of CdS to anode for water oxidation.
- Quantum dot,
- Photocathode,
- Cobaloxime,
- Photoelectrochemical cell,
- Water splitting
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沈阳化工大学材料科学与工程学院沈阳 110142