Citation: Rui Chen, Tie-Hong Chen. Facile synthesis of coordination polymer nanocubes and their conversion into mesoporous single crystal-like Y₂O₃ nanocubes[J]. Chinese Chemical Letters, ;2014, 25(6): 869-873. doi: 10.1016/j.cclet.2014.04.030 shu

Facile synthesis of coordination polymer nanocubes and their conversion into mesoporous single crystal-like Y₂O₃ nanocubes

Rui Chen ,
Tie-Hong Chen ^,

1.
Institute of New Catalytic Materials Science, Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

Corresponding author: Tie-Hong Chen,
Received Date: 4 March 2014
Available Online: 14 April 2014
Fund Project: This work was supported by NSFC (No. 21373116) (No. 21373116) Tianjin Natural Science Research Fund (No. 13JCYBJC18300) (No. 13JCYBJC18300) RFDP (No. 20120031110005) (No. 20120031110005)MOE Innovation Team (No. IRT13022) of China. (No. IRT13022)

Mesoporous single crystal-like Y₂O₃ nanocubes have been prepared through a coordination-based selfassembly process. Firstly, a uniform nanocube-like Y-lysine precursor was simply prepared with hydrothermal treatment. After the simple thermal treatment process, nanocube-shaped yttrium oxides with the morphology inherited from the Y-lysine precursor were successfully prepared. The phase, morphology, size and crystalline structure were well characterized by XRD, SEM and TEM. N₂ adsorption-desorption demonstrates the mesoporous characteristics of the Y₂O₃ nanocubes, showing a relatively high surface area of 60 m²/g.
- Mesoporous,
- Y₂O₃,
- Single crystal,
- Nanocube,
- Template-free
1. [1]
  [1] L.H. Chen, X.Y. Li, J.C. Rooke, et al., Hierarchically structured zeolites: synthesis, mass transport properties and applications, J. Mater. Chem. 22 (2012) 17381-17403.
2. [2]
  [2] L.N. Jin, Q. Liu, W.Y. Sun, Room temperature solution-phase synthesis of flowerlike nanostructures of [Ni₃(BTC)₂•12H₂O] and their conversion to porous NiO, Chin. Chem. Lett. 24 (2013) 663-667.
3. [3]
  [3] Y.F. Shi, Y. Wan, D.Y. Zhao, Ordered mesoporous non-oxide materials, Chem. Soc. Rev. 40 (2011) 3854-3878.
4. [4]
  [4] P.D. Yang, D.Y. Zhao, D.I. Margolese, B.F. Chmelka, G.D. Stucky, Block copolymer templating syntheses of mesoporous metal oxides with large ordering lengths and semicrystalline framework, Chem. Mater. 11 (1999) 2813-2826.
5. [5]
  [5] A.M. Spokoyny, D. Kim, A. Sumrein, C.A. Mirkin, Infinite coordination polymer nano-and microparticle structures, Chem. Soc. Rev. 38 (2009) 1218-1227.
6. [6]
  [6] M.Y. Masoomi, A. Morsali, Applications of metal-organic coordination polymers as precursors for preparation of nano-materials, Coord. Chem. Rev. 256 (2012) 2921-2943.
7. [7]
  [7] J. Wang, J. Wu, J. Lin, et al., Application of Y₂O₃:Er³⁺ nanorods in dye-sensitized solar cells, ChemSusChem 5 (2012) 1307-1312.
8. [8]
  [8] J.B. Ma, Z.C. Wang, M. Schlangen, S.G. He, H. Schwarz, Thermal reactions of YAlO3 with methane: increasing the reactivity of Y₂O₃ and the selectivity of Al2O3, Angew. Chem. Int. Ed. 51 (2012) 5991-5994.
9. [9]
  [9] Q. Dai, M.E. Foley, C.J. Breshike, A. Lita, G.F. Strouse, Ligand-passivated Eu:Y₂O₃ nanocrystals as a phosphor for white light emitting diodes, J. Am. Chem. Soc. 133 (2011) 15475-15486.
10. [10]
  [10] Y.J.O. Asencios, C.B. Rodella, E.M. Assaf, Oxidative reforming of model biogas over NiO-Y₂O₃-ZrO₂ catalysts, Appl. Catal. B 132-133 (2013) 1-12.
11. [11]
  [11] M.H. Abadi, M.N. Hamidon, A.H. Shaari, et al., Characterization of mixed xWO₃(1-x)Y₂O₃ nanoparticle thick film for gas sensing application, Sensors (Basel) 10 (2010) 5074-5089.
12. [12]
  [12] Y. Zhang, S. Pan, X. Teng, Y. Luo, G. Li, Bifunctional magnetic-luminescent nanocompositesY₂O₃/Tb nanorods on the surface of iron oxidesilica core-shell nanostructures, J. Phys. Chem. C 112 (2008) 9623-9626.
13. [13]
  [13] Y.B. Mao, J.Y. Huang, R. Ostroumov, K.L. Wang, J.P. Chang, Synthesis and luminescence properties of erbiuμ-doped Y₂O₃ nanotubes, J. Phys. Chem. C 112 (2008) 2278-2285.
14. [14]
  [14] G. Jia, M. Yang, Y.H. Song, H.P. You, H.J. Zhang, General and facile method to prepare uniform Y₂O₃-Eu hollow spheres, Cryst. Growth. Des. 9 (2009) 301-307.
15. [15]
  [15] R. Si, Y.W. Zhang, L.P. You, C.H. Yan, Rare-earth oxide nanopolyhedra, nanoplates, and nanodisks, Angew. Chem. Int. Ed. Engl. 117 (2005) 3320-3324.
16. [16]
  [16] S. Huang, J. Xu, Z. Zhang, et al., Rapid, morphologically controllable, large-scale synthesis of uniform Y(OH)3 and tunable luminescent properties of Y₂O₃:Yb³⁺/³⁺(Ln=Er, Tm and Ho), J. Mater. Chem. 22 (2012) 16136-16144.
17. [17]
  [17] R.V. Mangalaraja, J. Mouzon, P. Hedström, et al., Combustion synthesis of Y₂O₃ and Yb-Y₂O₃, J. Mater. Proc. Technol. 208 (2008) 415-422.
18. [18]
  [18] V.V. Rajasekharan, D.A. Buttry, Electrochemical synthesis of yttrium oxide nanotubes, Chem. Mater. 18 (2006) 4541-4543.
19. [19]
  [19] G. Mialon, M. Gohin, T. Gacoin, J.P. Boilot, High temperature strategy for oxide nanoparticle synthesis, ACS Nano 2 (2008) 2505-2512.
20. [20]
  [20] X. Qin, T. Yokomori, Y. Ju, Flame synthesis and characterization of rare-earth (Er³⁺, Ho³⁺, and Tm³⁺) doped upconversion nanophosphors, Appl. Phys. Lett. 90 (2007) 073104.
21. [21]
  [21] D.H.M. Buchold, C. Feldmann, Microemulsion approach to non-agglomerated and crystalline nanomaterials, Adv. Funct. Mater. 18 (2008) 1002-1011.
22. [22]
  [22] Z. Huo, C. Chen, Y. Li, Self-assembly of uniform hexagonal yttrium phosphate nanocrystals, Chem. Commun. (Camb.) (2006) 3522-3524.
23. [23]
  [23] S. Yin, S. Akita, M. Shinozaki, R. Li, T. Sato, Synthesis and morphological control of rare earth oxide nanoparticles by solvothermal reaction, J. Mater. Sci. 43 (2007) 2234-2239.
24. [24]
  [24] A.M. Petrosyan, V.V. Ghazaryan, Vibrational spectra of L-lysine monohydrochloride dihydrate and its two anhydrous forms, J. Mol. Struct. 917 (2009) 56-62.
25. [25]
  [25] T. Gougousi, Z. Chen, Deposition of yttrium oxide thin films in supercritical carbon dioxide, Thin Solid Films 516 (2008) 6197-6204.
26. [26]
  [26] Y.F. Lin, J.H. Chen, S.H. Hsu, T.W. Chung, Hydrothermal synthesis of Lewis acid Y₂O₃ cubes and flowers for the removal of phospholipids from soybean oil, CrystEngComm 15 (2013) 6506-6510.
27. [27]
  [27] W.W. Cai, H. Huang, X.Z. Guo, A facile one-step route to synthesize titania hollow microspheres with incontinuous multicavities, Chin. Chem. Lett. 25 (2014) 441-446.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Facile synthesis of coordination polymer nanocubes and their conversion into mesoporous single crystal-like Y2O3 nanocubes

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通讯作者: 陈斌, bchen63@163.com

Facile synthesis of coordination polymer nanocubes and their conversion into mesoporous single crystal-like Y₂O₃ nanocubes