Citation: Li-E. Dong, Guo-Jing Gou, Xue-Qin Jin, Min Zhang. Synthesis pretreatment and characterization of a magnetic layered double hydroxides fluorescent probe[J]. Chinese Chemical Letters, ;2014, 25(6): 923-928. doi: 10.1016/j.cclet.2014.03.006 shu

Synthesis pretreatment and characterization of a magnetic layered double hydroxides fluorescent probe

1.
Medical Chemistry Department, School of Basic Medical, Ningxia Medical University, Yinchuan 750004, China

Corresponding author: Guo-Jing Gou,
Received Date: 5 January 2014
Available Online: 27 February 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. 81260483, 20961008). (Nos. 81260483, 20961008)

Usingmagnetic layered double hydroxide (MLDH) as carrier of fluorescein (FLU), a fluorescent composite of MLDH-FLU was prepared via intercalation reaction of ion change. The crystal properties of MLDH-FLU were investigated through XRD, IR, TEM and TG-DSC characterization. It is shown that the crystal type of MLDH-FLU composite matched well with R-hexagonal crystal system of MLDH, with crystal cell parameters of a, c and channel height h equal to 0.3199, 2.411 and 0.3267 nm respectively. The superabundant pigment adsorbed outside the composite should be cleared before interference with cells, but excessive wash would decrease stability and cause crystal phase transformation of MLDH.
- Magnetic layered double hydroxides,
- Fluorescein,
- Intercalation,
- Dyeing mark
1. [1]
  [1] J.H. Choy, S.Y. Kwak, J.S. Park, Y.J. Jeong, J. Portier, Intercalative nanohybrids of nucleoside monophosphates and DNA in layered metal hydroxide, J. Am. Chem. Soc. 121 (1999) 1399-1400.
2. [2]
  [2] J.H. Choy, S.Y. Kwak, Y.J. Jeong, J.S. Park, Inorganic layered double hydroxides as nonviral vectors, Angew. Chem. Int. Ed. 39 (2000) 4041-4045.
3. [3]
  [3] J.H. Choy, J.S. Park, Y.J. Jeong, S.Y. Kwak, Cellular uptake behavior of [gamma-P-32] labeled ATP-LDH nanohybrids, J. Mater. Chem. 11 (2001) 1671-1674.
4. [4]
  [4] G.Q. Wan, D.X. Li, C.F. Li, J. Xu, W.G. Hou, From Zn-Al layered double hydroxide to ZnO nanostructure: gradually etching by sodium hydroxide, Chin. Chem. Lett. 23 (2012) 1415-1418.
5. [5]
  [5] M.R. Pérez, I. Pavlovic, C. Barriga, et al., Uptake of Cu²⁺, Cd²⁺ and Pb²⁺ on Zn-Al layered double hydroxide intercalated with EDTA, Appl. Clay Sci. 32 (2006) 245-251.
6. [6]
  [6] G.J. Gou, F.J. Bao, H.P. Xu, Z.X. Zheng, Effects of drug release medium on layered double hydroxide carrier, Acta Phys. Chim. Sin. 24 (2008) 1675-1680.
7. [7]
  [7] M.Z. Wang, Y. Li, J.J. Ji, et al., Novel hybrids of Cu²⁺ ternary complexes of salicylidene-amino acid Schiff base with phenanthroline (or bipyridine) intercalated in Mg/Al-NO^3- layered double hydroxide, Chin. Chem. Lett. 24 (2013) 593-596.
8. [8]
  [8] G.J. Gou, H.P. Xu, J.P. Liu, Loading and in vitro release of acetylsalicylic acid via layered double hydroxides, Acta Chim. Sin. 67 (2009) 65-82.
9. [9]
  [9] K. Ladewig, M. Niebert, Z.P. Xu, P.G. Peter, Q.L. Gao, Controlled preparation of layered double hydroxide nanoparticles and their application as gene delivery vehicles, Appl. Clay Sci. 48 (2010) 280-289.
10. [10]
  [10] K.L. Xu, G.M. Chen, J.Q. Shen, Direct decarbonation of micrometer-scale layered double hydroxides without morphology damage, Chin. Chem. Lett. 23 (2012) 805-808.
11. [11]
  [11] J.M.R. Génin, C. Ruby, Anion and cation distributions in Fe(II-III) hydroxysalt green rusts from XRD and Mössbauer analysis (carbonate, chloride, sulphate, ...);the "fougerite" mineral, Solid State Sci. 6 (2004) 705-718.
12. [12]
  [12] G.J. Gou, F.J. Bao, J.H. Yang, Preparation of Magnetic LDH with a Nitrogen-Hydrogen Preserve Co-Precipitation Method, CN 101607088B, 2009.
13. [13]
  [13] G.J. Gou, F.J. Bao, Y.X. Jiang, Preparation of the Magnetic Targeted and Extended Release Tri-Polymer with a Packed Structure of "Dextran-Magnetic LDH-Fluorouracil", CN 101607091B, 2011.
14. [14]
  [14] G.J. Gou, Y.H. Liu, Y. Sun, et al., The supra-molecular assembly and magnetic targeted slow-release effect of "dextran-magnetic layered double hydroxidefluorouracil" drug delivery system, Acta Pharm. Sin. 46 (2011) 1390-1398.
15. [15]
  [15] G.J. Gou, Z.Y. Wang, Y.H. Liu, et al., The supra-molecular assembly characterization and urgent toxic level of "dextran-magnetic layered double hydroxide-fluorouracil" drug delivery system, Acta Chim. Sin. 70 (2012) 161-169.
16. [16]
  [16] J. Huang, G.J. Gou, B. Xue, et al., Preparation and characterization of "dextranmagnetic layered double hydroxide-fluorouracil" targeted liposomes, Int. J. Pharm. 450 (2013) 323-330.
17. [17]
  [17] J. Huang, B. Xue, G.J. Gou, Study on cytotoxicity of "dextran-magnetic layered double hydroxide-fluorouracil" targeted liposomes in vitro, Appl. Mech. Mater. 320 (2013) 526-528.
18. [18]
  [18] Y.H. Liu, G.J. Gou, Containment proliferation and induction apoptosis effect of DMF drug delivery system on human colon cancer cells SW 480, Chin. Pharm. J. 48 (2013) 359-367.
19. [19]
  [19] D. Samuel, R.J. Patt, R.A. Abuknesha, A sensitive method of detecting proteins on dot and western blots using a monoclonal antibody to FITC, J. Immunol. Methods 107 (1988) 217-224.
20. [20]
  [20] J.M. Oh, S.J. Choi, S.T. Kim, Cellular uptake mechanism of an inorganic nanovehicle and its drug conjugates: enhanced efficacy due to clathrin-mediated endocytosis, Bioconjugate Chem. 17 (2006) 1411-1417.
21. [21]
  [21] D. Yan, J. Lu, M. Wei, D.G. Evans, X. Duan, Sulforhodamine B intercalated layered double hydroxide thin film with polarized photoluminescence, J. Phys. Chem. B 113 (2009) 1381-1389.
22. [22]
  [22] J.M. Oh, S.J. Choi, G.E. Lee, J.E. Kim, J.H. Choy, Nanoparticle uptake: inorganic metal hydroxide nanoparticles for targeted cellular uptake through clathrin-mediated endocytosis, Chem.: Asian J. 4 (2009) 67-73.
23. [23]
  [23] Z.P. Xu, M. Niebert, K. Porazik, et al., Subcellular compartment targeting of layered double hydroxide nanoparticle, J. Control. Release 130 (2008) 86-94.
24. [24]
  [24] A.W. Musumeci, G.M. Mortimer, M.K. Butler, et al., Fluorescent layered double hydroxide nanoparticles for biological studies, Appl. Clay Sci. 48 (2010) 271-279.
25. [25]
  [25] G.J. Gou, Y. Sun, F.Y. Zhang, et al., A fluorescent probe constituted with intercalation assembly of magnetic layered double hydroxide and fluorescein, CN 103289678A, 2013.
26. [26]
  [26] G.J. Gou, P.H. Ma, M.X. Chu, Kinetics of synthetic of Cl^- type hydrotalcite like with coprecipitation reaction, Acta Phys. Chim. Sin. 20 (2004) 1357-1363.
27. [27]
  [27] X.Y. Ren, Y. Xue, J. Liang, L.S. Ding, X. Liao, Selective extraction of flavonoids from Ginkgo biloba leaves using human serum albumin functionalized magnetic nanoparticles, Chin. Chem. Lett. 24 (2013) 1099-1102.
28. [28]
  [28] M.C. Zhang, Q. Zhou, Y. Zhou, A.M. Li, C.D. Shuang, Efficient adsorption and desorption of Cu2+ by a novel acid-resistant magnetic weak acid resin, Chin. Chem. Lett. 23 (2012) 1267-1270.
1. [1]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
2. [2]
  Yaru Geng , Ruiqing Li , Tingting Zhu , Xinling Li , Qianwen Guan , Huang Ye , Peng Wang , Junlin Li , Junhua Luo . Formamidine intercalation to broaden photoresponsive range in alternating-cations-interlayered hybrid perovskite. Chinese Chemical Letters, 2025, 36(8): 110216-. doi: 10.1016/j.cclet.2024.110216
3. [3]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
4. [4]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
5. [5]
  Jinglin CHENG , Xiaoming GUO , Tao MENG , Xu HU , Liang LI , Yanzhe WANG , Wenzhu HUANG . NiAlNd catalysts for CO₂ methanation derived from the layered double hydroxide precursor. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1592-1602. doi: 10.11862/CJIC.20240152
6. [6]
  Hui Yang , Guangxun Zhang , Yueyao Sun , Huijie Zhou , Huan Pang . Bimetallic zeolitic imidazolate framework derived hollow layered double hydroxide with tailorable interlayer spacing for nickel-zinc batteries. Chinese Chemical Letters, 2025, 36(6): 110016-. doi: 10.1016/j.cclet.2024.110016
7. [7]
  Zhu Wang , Shuangqiu Huang , Danni Guo , Wenhao Lao , Yiping Feng , Tong Li , Zhao-Qing Liu , Chun Hu . Reductive sequestration of Cr(Ⅵ) from water by an all-in-one polypyrrole/NiFe-layered double hydroxide filter. Chinese Chemical Letters, 2025, 36(12): 111090-. doi: 10.1016/j.cclet.2025.111090
8. [8]
  Jinqiang Gao , Haifeng Yuan , Xinjuan Du , Feng Dong , Yu Zhou , Shengnan Na , Yanpeng Chen , Mingyu Hu , Mei Hong , Shihe Yang . Methanol steam mediated corrosion engineering towards high-entropy NiFe layered double hydroxide for ultra-stable oxygen evolution. Chinese Chemical Letters, 2025, 36(1): 110232-. doi: 10.1016/j.cclet.2024.110232
9. [9]
  Yimin Guo , Yiting Luo , Shuwen Hua , Chuan-Fan Ding , Yinghua Yan . Application of magnetic nanomaterials in peptidomics: A review in the past decade. Chinese Chemical Letters, 2025, 36(6): 110070-. doi: 10.1016/j.cclet.2024.110070
10. [10]
  Jiajia Zhuang , Chunyu Cui , Changjiang Li , Gang Luo , Jiaping Tong , Di Sun . Counter-ion effect to the Ising-type magnetic anisotropy and magnetic relaxation in trigonal bipyramidal Co(Ⅱ) complexes. Chinese Chemical Letters, 2025, 36(7): 110091-. doi: 10.1016/j.cclet.2024.110091
11. [11]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
12. [12]
  Hailong He , Wenbing Wang , Wenmin Pang , Chen Zou , Dan Peng . Double stimulus-responsive palladium catalysts for ethylene polymerization and copolymerization. Chinese Chemical Letters, 2024, 35(7): 109534-. doi: 10.1016/j.cclet.2024.109534
13. [13]
  Di ZHANG , Tianxiang XIE , Xu HE , Wanyu WEI , Qi FAN , Jie QIAO , Gang JIN , Ningbo LI . Construction and antitumor activity of pH/GSH dual-responsive magnetic nanodrug. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 786-796. doi: 10.11862/CJIC.20240329
14. [14]
  Ke Xu , Shulai Lei , Panshuo Wang , Weiyi Wang , Yuan Feng , Junsheng Feng . Unraveling the microscopic origin of out of plane magnetic anisotropy in Ⅵ₃. Chinese Chemical Letters, 2025, 36(8): 110257-. doi: 10.1016/j.cclet.2024.110257
15. [15]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
16. [16]
  Chao Ma , Peng Guo , Zhongmin Liu . DNL-16: A new zeolitic layered silicate unraveled by three-dimensional electron diffraction. Chinese Journal of Structural Chemistry, 2024, 43(4): 100235-100235. doi: 10.1016/j.cjsc.2024.100235
17. [17]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426
18. [18]
  Yongjian Li , Xinyu Zhu , Chenxi Wei , Youyou Fang , Xinyu Wang , Yizhi Zhai , Wenlong Kang , Lai Chen , Duanyun Cao , Meng Wang , Yun Lu , Qing Huang , Yuefeng Su , Hong Yuan , Ning Li , Feng Wu . Unraveling the chemical and structural evolution of novel Li-rich layered/rocksalt intergrown cathode for Li-ion batteries. Chinese Chemical Letters, 2024, 35(12): 109536-. doi: 10.1016/j.cclet.2024.109536
19. [19]
  Qiang Wu , Baofeng Wang . Exploring synthetic strategy for stabilizing nickel-rich layered oxide cathodes through structural design. Chinese Chemical Letters, 2024, 35(12): 110089-. doi: 10.1016/j.cclet.2024.110089
20. [20]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1218)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142