Citation: Mohammad Reza Pourjavid, Ali Akbari Sehat, Majid Haji Hosseini, Mohammad Rezaee, Masoud Arabieh, Seyed Reza Yousefi, Mohammad Reza Jamali. Use of 2-(tert-butoxy)-N-(3-carbamothioylphenyl)acetamide and graphene oxide for separation and preconcentration of Fe(Ⅲ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) ions in different samples[J]. Chinese Chemical Letters, ;2014, 25(05): 791-793. doi: 10.1016/j.cclet.2014.01.045 shu

Use of 2-(tert-butoxy)-N-(3-carbamothioylphenyl)acetamide and graphene oxide for separation and preconcentration of Fe(Ⅲ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) ions in different samples

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a NFCRS, Nuclear Science & Technology Research Institute, AEOI, Tehran 11365-8486, Iran;
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b Department of Analytical Chemistry, Faculty of Chemistry, University College of Science, University of Tehran, Tehran 14155-6455, Iran;
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c Department of Chemistry, Payame Noor University, Tehran 19395-3697, Iran

Corresponding author: Mohammad Reza Pourjavid,
Received Date: 19 December 2013
Available Online: 21 January 2014

A simple and selective method using a column packed with graphene oxide (GO) as a solid phase extractant has been developed for the multi-element preconcentration of Fe(Ⅲ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) ions prior to flame atomic absorption spectrometric determinations. The method is based on the sorption of mentioned ions on synthesized GO using 2-(tert-butoxy)-N-(3-carbamothioylphenyl)acetamide as a chelating agent. Several parameters on the extraction and complex formation were optimized. Under the optimized conditions (pH 6, flow rate 9 mL/min), metal ions were retained on the column, then quantitatively eluted by HNO₃ solution (5 mL, 3.0 mol/L). The preconcentration factor was calculated as 250. The detection limits for the analyte ions of interest were found in the range of 0.11 ng/mL (Ni²⁺) to 0.63 ng/mL (Cu²⁺). The column packed with GO was adequate for metal ions separation in matrixes containing alkali, alkaline earth, transition and heavy metal ions.
- Solid phase extraction,
- Transition metals,
- Graphene oxide,
- Flame atomic absorption spectrometry
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沈阳化工大学材料科学与工程学院沈阳 110142