Citation: Qing-Yun Liu, Qing-Yan Jia, Ji-Qin Zhu, Qian Shao, Jun-Feng Fan, Dong-Mei Wang, Yan-Sheng Yin. Highly ordered arrangement of meso-tetrakis(4-aminophenyl)porphyrin in self-assembled nanoaggregates via hydrogen bonding[J]. Chinese Chemical Letters, ;2014, 25(05): 752-756. doi: 10.1016/j.cclet.2013.12.023 shu

Highly ordered arrangement of meso-tetrakis(4-aminophenyl)porphyrin in self-assembled nanoaggregates via hydrogen bonding

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a College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China;
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b College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266510, China;
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c Institute of Marine Materials Science and Engineering, Shanghai Maritime University, Shanghai 201306, China

Corresponding author: Qing-Yun Liu, Yan-Sheng Yin,
Received Date: 6 November 2013
Available Online: 30 December 2013
Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos. 51042013, 21271119) (Nos. 51042013, 21271119) Innovation Fund of Shanghai (No. 10170502400) (No. 10170502400) and Research Progect of "SUST Spring Bud" (No. 2008BWZ056). (No. J08LC11)

meso-Tetrakis(4-aminophenyl)porphyrin (TAPP) can self-assemble into nanostructures with different morphologies by a phase-transfer method. The morphologies (nanospheres, nanorods and nanothorns) of porphyrin nanoaggregates could be easily tuned just by changing the concentration of porphyrin in a proper solvent at room temperature. HRTEM images revealed the formation of highly ordered supramolecular arrays of TAPP, i.e., superlattice of TAPP molecules in nanoaggregates, which agreed well with the size of one molecule of TAPP. UV-vis absorption spectra showed an obvious red shift of the Soret band of TAPP, indicating the formation of J-aggregates of TAPP in nanoaggregates.
- Porphyrin,
- Self-assembly,
- Nanoaggregates,
- Highly ordered,
- Hydrogen bonding
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