Citation: Yong-Heng Shi, Ya-Fei Xie, Yu-Qiang Liu, Qun-Chao Wei, Wei-Ren Xu, Li-Da Tang, Gui-Long Zhao. SrCl₂ as an efficient cocatalyst for acidic hydrolysis of methyl glycosides[J]. Chinese Chemical Letters, ;2014, 25(4): 561-566. doi: 10.1016/j.cclet.2013.11.028 shu

SrCl₂ as an efficient cocatalyst for acidic hydrolysis of methyl glycosides

1.
a School of Pharmacy, Tianjin Medical University, Tianjin 300070, China;
2.
b Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin 300193, China

Corresponding author: Li-Da Tang, Gui-Long Zhao,
Received Date: 8 October 2013
Available Online: 12 November 2013
Fund Project: The authors are very grateful to the Natural Science Foundation of China (No. 21302141) (No. 21302141)

SrCl₂ was found to be the most efficient cocatalyst for the acidic hydrolysis of methyl glycosides after 26 kinds of most representative metal salts were screened. The SrCl₂-cocatalyzed acidic hydrolysis of methyl glycosides is highlighted by short reaction times, less byproducts and high yields. A possible mechanism for the SrCl₂-cocatalyzed hydrolysis is also proposed.
- Cocatalyst,
- Hydrolysis,
- Lewis acid,
- Methyl glycoside,
- Strontium chloride
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

SrCl2 as an efficient cocatalyst for acidic hydrolysis of methyl glycosides

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通讯作者: 陈斌, bchen63@163.com

SrCl₂ as an efficient cocatalyst for acidic hydrolysis of methyl glycosides