Citation: Yun Chuan Xiao, Jing Xie, Min Yu, Miao Liu, Jian Ran, Zhen Xi, Wei Li, Jing Huang. Bisabocurcumin, a new skeleton curcuminoid from the rhizomes of Curcuma longa L.[J]. Chinese Chemical Letters, ;2011, 22(12): 1457-1460. doi: 10.1016/j.cclet.2011.09.002
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A new skeleton bisabolane-type sesquiterpene curcuminoid, bisabocurcumin (1), along with 5 known compounds, curcumin (2), demethoxycurcumin (3), bidemethoxycurcumin (4), (1E, 4E)-l, 5-bis (4-hydroxy-3-methoxyphenyl)-penta-1, 4-dien-3-one (5), and (1E, 4E)-1-(4-hydroxy-3-methoxyphenyl)-5-(4-hydroxy phenyl-)-penta-1, 4-dien-3-one (6) were isolated from the rhizomes of Curcuma longa L. Their structures were determined on the basis of spectroscopic analysis. Bisabocurcumin (1) is firstly obtained from nature with a new skeleton combined by a bisabolane-type sesquiterpene and a 1, 7-diphenylheptanoid through a C-C bond.
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