Citation: Tao Wang, Shan Shi, Li Na Bian, Li Min Zhou, Li Qun Zhao, Shin Ichi Kuroda. Poly(2-acetoxyethyl methacrylate)/polystyrene latex interpenetrating polymer networks with well-defined phase-separated structure[J]. Chinese Chemical Letters, ;2011, 22(12): 1505-1508. doi: 10.1016/j.cclet.2011.06.004 shu

Poly(2-acetoxyethyl methacrylate)/polystyrene latex interpenetrating polymer networks with well-defined phase-separated structure

a Key Laboratory of Applied Technology of Polymer Materials, College of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China;
b Department of Production Science and Technology, Faculty of Engineering, Gunma University, Ota 373-0057, Japan

Received Date: 29 April 2011

Fund Project: This work was partially supported by National Natural Science Foundation of China (No.50943028) and Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry.

A series of poly (2-acetoxyethyl methacrylate)/polystyrene (PAEMA/PS) latex interpenetrating polymer networks (LIPNs) were prepared by seeded soap-free emulsion polymerization of styrene on the crosslinked PAEMA seed particles using an oil-soluble initiator. These PAEMA/PS LIPNs showed a well-defined phase-separated structure with PS phase dispersing in continuous PAEMA phase. The domain size of PS phase was found to depend on the crosslinking degree of PAEMA seed particles and the amount of second-stage styrene monomer.
- Phase-separation,
- IPN,
- Seeded soap-free emulsion polymerization,
- Crosslinking,
- Particle
1. [1]
  Tong Liu , Youdong Xu , Yajie Jiao , Jinguo Zhao , Bin Fu , Xianyu Li , Hongjun Yang , Weijie Qin . A dual-crosslinking and thiol-yne "click reaction"-based tagging method for mouse liver RNA binding proteome enrichment and identification by mass spectrometry. Chinese Chemical Letters, 2026, 37(1): 111154-. doi: 10.1016/j.cclet.2025.111154
2. [2]
  Wangyan Hu , Ke Li , Xiangnan Dou , Ning Li , Xiayan Wang . Nano-sized stationary phase packings retained by single-particle frit for microchip liquid chromatography. Chinese Chemical Letters, 2024, 35(4): 108806-. doi: 10.1016/j.cclet.2023.108806
3. [3]
  Fangzhou Li , Liang Gao , Linping Wang , Ben-Lin Hu . Unlocking the elasticity in ferroelectrics by slight crosslinking. Chinese Journal of Structural Chemistry, 2025, 44(3): 100443-100443. doi: 10.1016/j.cjsc.2024.100443
4. [4]
  Bei Li , Zhaoke Zheng . In situ monitoring of the spatial distribution of oxygen vacancies at the single-particle level. Chinese Journal of Structural Chemistry, 2024, 43(10): 100331-100331. doi: 10.1016/j.cjsc.2024.100331
5. [5]
  Hefei Yang , Le-Cheng Wang , Xiao-Feng Wu . Sustainable carbonylative transformation of alkyl iodides to amides via crosslinking of EDA and XAT. Chinese Chemical Letters, 2025, 36(9): 110843-. doi: 10.1016/j.cclet.2025.110843
6. [6]
  Yifei Zhang , Yuncong Xue , Laiwei Gao , Rui Liao , Feng Wang , Fei Wang . Merging non-covalent and covalent crosslinking: En route to single chain nanoparticles. Chinese Chemical Letters, 2024, 35(6): 109217-. doi: 10.1016/j.cclet.2023.109217
7. [7]
  Yingxiao Gao , Feng Feng , Ting Luo , Yusong Han , Mingxuan Wu . Development of site-selective photo crosslinking between tyrosine and sulfonium in methyllysine readers. Chinese Chemical Letters, 2025, 36(10): 110756-. doi: 10.1016/j.cclet.2024.110756
8. [8]
  Nan Wang , Lingling Wu , Yaya Su , Haifeng Tang , Hailong Yuan . Linking starch particle physicochemical properties to functionality in medicinal plants: Insights from Polygonum multiflorum and Smilax glabra. Chinese Chemical Letters, 2026, 37(1): 111270-. doi: 10.1016/j.cclet.2025.111270
9. [9]
  Xingqun Pu , Rongrong Liu , Yuting Xie , Chenjing Yang , Jingyi Chen , Baoling Guo , Chun-Xia Zhao , Peng Zhao , Jian Ruan , Fangfu Ye , David A Weitz , Dong Chen . One-step preparation of biocompatible amphiphilic dimer nanoparticles with tunable particle morphology and surface property for interface stabilization and drug delivery. Chinese Chemical Letters, 2025, 36(3): 109820-. doi: 10.1016/j.cclet.2024.109820
10. [10]
  Feng Xu , Yuqiu Liu , Shujiao Xu , Jinxin Zhang , Lei Liao , Jiguang Guo , Weiyu Jiang , Hongzhe Dong , Qinxue Wen , Zhiqiang Chen . Enhanced removal of methylisothiazolinone from high-salt wastewater by Sn-Sb-Ce/GAC particle electrode: Reactive species and efficiency. Chinese Chemical Letters, 2025, 36(10): 111332-. doi: 10.1016/j.cclet.2025.111332
11. [11]
  Yan Zou , Yin-Shuang Hu , Deng-Hui Tian , Hong Wu , Xiaoshu Lv , Guangming Jiang , Yu-Xi Huang . Tuning the membrane rejection behavior by surface wettability engineering for an effective water-in-oil emulsion separation. Chinese Chemical Letters, 2024, 35(6): 109090-. doi: 10.1016/j.cclet.2023.109090
12. [12]
  Bicheng Ji , Xicheng Li , Shuai Gao , Pengyuan Liu , Jiajie Bao , Lv Qian , Changzheng Wang , Qiang Wang , Chong-Chen Wang . In-situ Z-scheme hetero-phase homojunction significantly enhances the carrier separation efficiency of TiO₂ nanotube arrays: Key role of crystal phase engineering. Chinese Chemical Letters, 2026, 37(2): 111424-. doi: 10.1016/j.cclet.2025.111424
13. [13]
  Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan . Coating colloidal particles with a well-defined polymer layer by surface-initiated photoinduced polymerization-induced self-assembly and the subsequent seeded polymerization. Chinese Chemical Letters, 2025, 36(2): 110431-. doi: 10.1016/j.cclet.2024.110431
14. [14]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
15. [15]
  Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO₃₋_x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753
16. [16]
  Lei Li , Guang Yang , Tianbai Xiong , Tingzhu Duan , Jia Wang , Xin Wang . Metal-free click polymerization of thiols and chalcone-derived internal olefins in air to prepare functional clusteroluminescent polythioethers for dual-response fluorescent probe. Chinese Chemical Letters, 2025, 36(11): 111374-. doi: 10.1016/j.cclet.2025.111374
17. [17]
  Man Xu , Qianyi Li , Jingyao Ma , Hao Li , Yunfei Zhu , Fan Yu , Kuande Wang , Tao Zhou , Quanyou Feng , Linghai Xie , Jinyi Lin . Wide bandgap steric carbazole-fluorene-nanogrid polymers via metal-free CN polymerization for deep-blue polymer light-emitting diodes. Chinese Chemical Letters, 2026, 37(1): 111551-. doi: 10.1016/j.cclet.2025.111551
18. [18]
  Yan-Ran Weng , Wen-Fu Tian , Wen-Jing Ding , Bi-He Ren , De-Hou Liu , Jia-Ying Tang , Feng Zhou , Xiao-Gang Chen , Xian-Jiang Song , Hui-Peng Lv , Yong Ai . Homochiral organic ferroelastics with plastic phase transition. Chinese Chemical Letters, 2025, 36(7): 110188-. doi: 10.1016/j.cclet.2024.110188
19. [19]
  Pengcheng Su , Shizheng Chen , Zhihong Yang , Ningning Zhong , Chenzi Jiang , Wanbin Li . Vapor-phase postsynthetic amination of hypercrosslinked polymers for efficient iodine capture. Chinese Chemical Letters, 2024, 35(9): 109357-. doi: 10.1016/j.cclet.2023.109357
20. [20]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(1382)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return