Citation: Jing Yang, Le Xin Song, Zheng Dang, Shu Zhen Pan, Fang Yun Du. Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine[J]. Chinese Chemical Letters, ;2011, 22(11): 1347-1350. doi: 10.1016/j.cclet.2011.05.029 shu

Effect of noncovalent complexations on coordination interactions in a tricomponent system of β-cyclodextrin, copper chloride and hexamethylene tetramine

a Department of Chemistry, University of Science and Technology of China, Hefei 230026, China;
b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Received Date: 15 March 2011

Fund Project: This project was supported by NSFC (No.21071139).

This study reveals that the noncovalent complexation between β-CD and Cu(HMTA)²⁺ makes a positive contribution to the coordination interaction between Cu²⁺ and HMTA in a tricomponent system. Besides, mono-and binuclear complexes:[β-CD·Cu]⁺ and[Cu-β-CD·Cu)⁺ were observed under the condition of ESI-MS.
- Noncovalent complexation,
- Coordination interaction,
- β-Cyclodextrin,
- Copper chloride
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