Citation: Farhad Shirini, Meysam Alipour Khoshdel, Masoumeh Abedini, Seyyed Vahid Atghia. Nanocrystalline TiO₂ as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols[J]. Chinese Chemical Letters, ;2011, 22(10): 1211-1214. doi: 10.1016/j.cclet.2011.05.002 shu

Nanocrystalline TiO₂ as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols

Department of Chemistry, College of Science, University of Guilan, Rasht 41335, Islamic Republic of Iran

Received Date: 22 February 2011

Fund Project: We are thankful to the University of Guilan Research Council for the partial support of this work.

Nanocrystalline TiO₂ was used as an efficient and recyclable catalyst for the chemoselective trimethylsilylation of primary and less hindered secondary alcohols and phenols with hexamethyldisilazane (HMDS). All reactions were performed under mild and completely heterogeneous conditions in good to excellent yields.
- Nanocrystalline TiO₂,
- Trimethylsilylation,
- Alcohols,
- Phenols,
- Heterogeneous reaction conditions
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