Citation: Fa Wang Chen, Tao Dong, Xiao Fang Li, Tie Gang Xu, Chang Wen Hu. Tetrabutylammonium salts of tritransition-metal-substituted A-α-tungstogermanate:Halogen-free and single-component catalysts for the coupling reaction of carbon dioxide and epichlorohydrin[J]. Chinese Chemical Letters, ;2011, 22(7): 871-874. doi: 10.1016/j.cclet.2011.01.004 shu

Tetrabutylammonium salts of tritransition-metal-substituted A-α-tungstogermanate:Halogen-free and single-component catalysts for the coupling reaction of carbon dioxide and epichlorohydrin

a Key Laboratory of Cluster Science, Ministry of Education of China, Beijing Institute of Technology, Beijing 100081, China;
b School of Material Engineering, Jinling Institute of Technology, Nanjing 211169, China

Received Date: 19 October 2010

Fund Project: the Program of Cooperation of the Beijing Education Commission (No.20091739006)the 111 Project (No.B07012)This work was financially supported by the Natural Science Foundation of China (Nos.20731002 and 10876002)Specialized Research Fund for the Doctoral Program of Higher Education (No.200800070015)Postgraduate innovative Research Foundation of Beijing Institute of Technology (No.AA200804).

The green synthesis of chloropropylene carbonate via the coupling reaction of carbon dioxide and epichlorohydrin had been achieved using halogen-free and single-component catalysts tetrabutylammonium salts of tritransition-metal-substituted A-α-tungstogermanate [(n-C₄H₉)₄N]₃H₇GeW₉M₃(H₂O)₃O₃₇ (M = Cu^Ⅱ, Ni^Ⅱ, Co^Ⅱ and Mn^Ⅱ) without any solvent. The catalytic activity was significantly depended on the transition metal introduced in polyoxometalates. [(n-C₄H₉)₄N]₃H₇GeW₉Mn₃(H₂O)₃O₃₇ exhibited the highest catalytic activity with 94.9% conversion for epichlorohydrin and 98% selectivity for chloropropylene carbonate in 3 h. Plausible mechanism was proposed based on the results.
- Cyclic carbonate,
- Catalysis,
- Carbon dioxide,
- Polyoxometalates
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