Citation: Yuan Yuan Li, Wen Jing Zhao, Hua Cheng Zhang, Tao Sun, Wei An, Fei Fei Xin, Ai You Hao. Triple-transforming gel prepared by β-cyclodextrin,diphenylamine and lithium chloride in N,N-dimethylacetamide[J]. Chinese Chemical Letters, ;2010, 21(10): 1251-1254. doi: 10.1016/j.cclet.2010.04.018 shu

Triple-transforming gel prepared by β-cyclodextrin,diphenylamine and lithium chloride in N,N-dimethylacetamide

School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China

Received Date: 11 February 2010

This paper describes a triple-transforming gel system(gel-sol-gel')for the first time, which is a thermo-responsive and multicomponent organogel prepared by β-cyclodextrin (β-CD), diphenylamine(DPA)and lithium chloride (LiCl) in N, N-dimethylacetamide (DMAC) in a suitable proportion based on the supramolecular interactions. In the triple-transforming gel system, a gel (gel A) could be formed by β-CD, DPA and LiCl in DMAC at room temperature based on stirring, then the gel could transform into a clear solution based on heating, and then the other gel (gel B) can be formed at a relatively high temperature(T_gel, the gelation temperature by heating). The two gel states in the triple-transforming gel system have different microstructures. This gel system was characterized by OM, SEM, IR and rheology.
- Gel,
- Triple-transforming,
- β-Cyclodextrin,
- Lithium,
- N,N-Dimethylacetamide
1. [1]
  Qinwei Lu , Jinjie Lu , Juying Lei , Xubiao Luo , Yanbo Zhou . Cyclodextrin-boosted photocatalytic oxidation for efficient bisphenol A removal. Chinese Chemical Letters, 2025, 36(3): 110017-. doi: 10.1016/j.cclet.2024.110017
2. [2]
  Hongfei Li , Hao Chen , Qi Kang , Lihe Guo , Xingyi Huang , Haiping Xu . Gel polymer electrolyte for flexible and stretchable lithium metal battery: Advances and prospects. Chinese Chemical Letters, 2025, 36(9): 110325-. doi: 10.1016/j.cclet.2024.110325
3. [3]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
4. [4]
  Mengya Ge , Zijie Zhou , Huaiyang Zhu , Ying Wang , Chao Wang , Chao Lai , Qinghong Wang . Multifunctional gel electrolytes for high-performance zinc metal batteries. Chinese Chemical Letters, 2025, 36(7): 110121-. doi: 10.1016/j.cclet.2024.110121
5. [5]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
6. [6]
  Chong Tang , Zhong Qiu , Chen Li , Tengfei Zhang , Renhong Chen , Yifa Sheng , Xinhui Xia , Yongqi Zhang , Jun Liu . Rational synthesis of vertical graphene supported TiN@N-Li₄Ti₅O₁₂ as advanced high-rate electrodes for lithium-ion batteries. Chinese Chemical Letters, 2025, 36(11): 110589-. doi: 10.1016/j.cclet.2024.110589
7. [7]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
8. [8]
  Siwei Wang , Wei-Lei Zhou , Yong Chen . Cucurbituril and cyclodextrin co-confinement-based multilevel assembly for single-molecule phosphorescence resonance energy transfer behavior. Chinese Chemical Letters, 2024, 35(12): 110261-. doi: 10.1016/j.cclet.2024.110261
9. [9]
  Linnan Jiang , Zhenkai Qian , Yong Chen , Xiaoyong Yu , Yugui Qiu , Wen-Wen Xu , Yonghui Sun , Xiufang Xu , Lihua Wang , Yu Liu . Double response reversible phosphorescence based on cyclodextrin supramolecular flexible elastic achieved multicolor delayed fluorescence. Chinese Chemical Letters, 2025, 36(8): 110676-. doi: 10.1016/j.cclet.2024.110676
10. [10]
  Mengxiao Yang , Haicheng Huang , Shiyi Shen , Xinxin Liu , Mengyu Liu , Jiahua Guo , Fenghui Yang , Baoli Zha , Jiansheng Wu , Sheng Li , Fengwei Huo . Flexible aqueous zinc-ion battery with low-temperature resistant leather gel electrolyte. Chinese Chemical Letters, 2025, 36(6): 109988-. doi: 10.1016/j.cclet.2024.109988
11. [11]
  Chanqi Ye , Jia Zhang , Jie Shen , Ruyin Chen , Qiong Li , Peng Zhao , Dong Chen , Jian Ruan . Attractive Pickering emulsion gel loaded with oxaliplatin and lactate dehydrogenase inhibitor increases the anti-tumor effect in hepatocellular carcinoma. Chinese Chemical Letters, 2025, 36(7): 110519-. doi: 10.1016/j.cclet.2024.110519
12. [12]
  Aijia Zhang , Guiyuan Zhao , Guangli Xiang , Rui Chen , Yu Dong , Qijie Diao , Jialin Wang , Xiaohui Lin , Wenxuan Zeng , Tianze Jiang , Jun Wu , Xia Zhao . Barnacle-inspired chitosan glycerin gel for skin protection and wound healing in harsh environments. Chinese Chemical Letters, 2025, 36(8): 110767-. doi: 10.1016/j.cclet.2024.110767
13. [13]
  Wenjia Wang , Xingyue He , Xiaojie Wang , Tiantian Zhao , Osamu Muraoka , Genzoh Tanabe , Weijia Xie , Tianjiao Zhou , Lei Xing , Qingri Jin , Hulin Jiang . Glutathione-depleted cyclodextrin pseudo-polyrotaxane nanoparticles for anti-inflammatory oxaliplatin (Ⅳ) prodrug delivery and enhanced colorectal cancer therapy. Chinese Chemical Letters, 2024, 35(4): 108656-. doi: 10.1016/j.cclet.2023.108656
14. [14]
  Chun-Ying Xu , Xiao-Lin Luan , Yuan-Yuan Cui , Cheng-Xiong Yang . One-pot in situ doping synthesis of phenylboronic acid-functionalized magnetic-cyclodextrin microporous organic network for specific enrichment and detection of sulfonylurea herbicides. Chinese Chemical Letters, 2025, 36(9): 110937-. doi: 10.1016/j.cclet.2025.110937
15. [15]
  Mengwen Wang , Qintao Sun , Yue Liu , Zhengan Yan , Qiyu Xu , Yuchen Wu , Tao Cheng . Impact of lithium nitrate additives on the solid electrolyte interphase in lithium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(2): 100203-100203. doi: 10.1016/j.cjsc.2023.100203
16. [16]
  Ting Hu , Yuxuan Guo , Yixuan Meng , Ze Zhang , Ji Yu , Jianxin Cai , Zhenyu Yang . Uniform lithium deposition induced by copper phthalocyanine additive for durable lithium anode in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108603-. doi: 10.1016/j.cclet.2023.108603
17. [17]
  Tao Wei , Jiahao Lu , Pan Zhang , Qi Zhang , Guang Yang , Ruizhi Yang , Daifen Chen , Qian Wang , Yongfu Tang . An intermittent lithium deposition model based on bimetallic MOFs derivatives for dendrite-free lithium anode with ultrahigh areal capacity. Chinese Chemical Letters, 2024, 35(8): 109122-. doi: 10.1016/j.cclet.2023.109122
18. [18]
  Shu Lin , Kezhen Qi . Phase-dependent lithium-alloying reactions for lithium-metal batteries. Chinese Chemical Letters, 2024, 35(4): 109431-. doi: 10.1016/j.cclet.2023.109431
19. [19]
  Dong Sui , Jiayi Liu . Constriction-susceptible lithium support for fast cycling of solid-state lithium metal battery. Chinese Chemical Letters, 2025, 36(2): 110417-. doi: 10.1016/j.cclet.2024.110417
20. [20]
  Qihou Li , Jiamin Liu , Fulu Chu , Jinwei Zhou , Jieshuangyang Chen , Zengqiang Guan , Xiyun Yang , Jie Lei , Feixiang Wu . Coordinating lithium polysulfides to inhibit intrinsic clustering behavior and facilitate sulfur redox conversion in lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(5): 110306-. doi: 10.1016/j.cclet.2024.110306

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1165)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return