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Citation:
Wei Wu, Xiao Yun Zhang, Shou Xing Kang, Yan Min Gao. Tri(t-butyl)phosphine-assisted selective hydrosilylation of terminal alkyne[J]. Chinese Chemical Letters,
;2010, 21(3): 312-316.
doi:
10.1016/j.cclet.2009.11.040
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A highly efficient and regio-/stereoselective method of hydrosilylating terminal alkynes was developed using Pt(DVDS)-tri(t-butyl)phosphine catalyst system at room temperature. Trans-products or alpha-products were obtained almost exclusively depending on the alkynes and silanes employed.
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Keywords:
- Hydrosilylation,
- Terminal alkynes,
- Tri(t-butyl)phosphine,
- Platinum
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