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Citation: Mohsen Nikpour, Hossein Eshtiagh-Hosseini, Masoud Mirzaei, Amir Aghaei Kaju, Ya Guang Chen, Soroush Zarinabadi. An ionic 2D inorganic-organic hybrid of tris[((1H-tetrazol-5-yl)methyl)morpholine]dodecatungstophosphate(Ⅴ)pentahydrate:Synthesis X-ray crystal structure and spectroscopic characterizations[J]. Chinese Chemical Letters, ;2010, 21(4): 501-505. doi: 10.1016/j.cclet.2009.11.024 shu

An ionic 2D inorganic-organic hybrid of tris[((1H-tetrazol-5-yl)methyl)morpholine]dodecatungstophosphate(Ⅴ)pentahydrate:Synthesis X-ray crystal structure and spectroscopic characterizations

a Department of Chemistry, School of Sciences, Islamic Azad University, Ahvaz Branch, Ahvaz 61349-68875, Iran;
b Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, Mashhad, P. O. Box 917791436, Iran;
c Department of Chemistry, Khorassan Science & Technology Park, Mashhad, P. O. Box 91735139, Iran;
d Faculty of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun 130024, China

Fund Project: The financial support of this research by Islamic Azad University, Ahvaz Branch, is gratefully acknowledged. We are grateful to Faculty of Chemistry, Northeast Normal University of China for determining the structural analysis by single-crystal X-ray diffraction method.

A unique ionic hybrid material[C₆H₁₂N₅O]₃[(PO₄)W₁₂O₃₆]·5H₂O has been synthesized from the reaction of((1H-tetrazole-5-yl)morphline and α-H₃ [(PO₄)W₁₂O₃₆]·21H₂O.It has successfully been charactrized by elemental analysis.IR and ¹HNMR spectroscopies,TGA and single-crystal X-ray diffraction method.Thetitle compound is constructed from the three [C₆H₁₂N₅O]⁺cations and α-Keggin[(PO₄)W₁₂O₃₆]^3-polyoxoanion.The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like(2D/∞[(PO₄)W₁₂O₃₆]^3-)which forming via van der Waais interactions along the x axis.
- Polyoxometalate,
- Inorganic-organic hybrid,
- Morpholine,
- Dodecatungstophosphate,
- Crystal structure
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