Citation: Cheng Deng, Yong Cai Song, Ying De Wang, Yi He Li, Yong Peng Lei, Shu Wei Cao. A facile synthesis of 2,4,6-trichloroborazine from boron trichloride-dimethylsulfide complex and ammonium chloride[J]. Chinese Chemical Letters, ;2010, 21(2): 135-138. doi: 10.1016/j.cclet.2009.10.016 shu

A facile synthesis of 2,4,6-trichloroborazine from boron trichloride-dimethylsulfide complex and ammonium chloride

a State Key Laboratory of Advanced Ceramic Fibers & Composites, College of Aerospace and Materials Engineering, National University of Defense Technology, Changsha 410073, China;
b Aerospace Research Institute of Materials & Processing Technology, Beijing 100076, China

Received Date: 2 June 2009

Fund Project: We wish to thank the National "863" Program (No. 2006AA03A217) for financial support of the research.

2,4,6-Trichloroborazine has been recognized as a desirable monomer for the preparation of high-performance boron nitride fibers through polymer derived ceramics route.So a high yield and facile synthesis of 2,4,6-trichloroborazine is essential in practice.Using boron trichloride-dimethylsulfide complex((CH₃)₂S·BCl₃)and ammonium chloride(NH₄Cl)as starting materials and toluene(C₆H₅CH₃)as solvent,the synthesis of 2,4,6-trichloroborazine to give high yield is reported.(C)2009 Cheng Deng.Published by Elsevier B.V.on behalf of Chinese Chemical Society.All rights reserved.
- 2,4,6-Trichloroborazine,
- Boron trichloride-dimethylsulfide,
- Boron nitride precursor,
- Synthesis
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