Citation: Shahnaz Rostamizadeh, Hamid Ghaieni, Reza Aryan, Ali Amani. Zinc chloride catalyzed synthesis of 5-substituted 1H-tetrazolesunder solvent free condition[J]. Chinese Chemical Letters, ;2009, 20(11): 1311-1314. doi: 10.1016/j.cclet.2009.06.020 shu

Zinc chloride catalyzed synthesis of 5-substituted 1H-tetrazolesunder solvent free condition

a Department of Chemistry, Faculty of Sciences, K.N. Toosi University of Technology, P.O. Box:15875-4416, Tehran, Iran;
b Faculty of Material and Chemical Engineering, Malek Ashtar University of Technology, Tehran, Iran

Received Date: 30 March 2009

Zinc chloride is an efficient and safe catalyst in the [3+2] cycloaddition reaction of organic nitriles with sodium azide in solventless condition. The corresponding 5-substituted 1H tetrazoles were obtained under mild conditions. This method can overcome disadvantages such as:the use of toxic metals and expensive reagents, drastic reaction conditions, water sensitivity and the presence of dangerous hydrazoic acid.
- 5-Substituted 1H-tetrazoles,
- Zinc chloride,
- Sodium azide,
- Solvent free
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