Citation: Reza Heydari Malek Taher Maghsoodlou, Razieh Nejat Yami. An efficient method for synthesis of organophosphorus compounds in aqueous media[J]. Chinese Chemical Letters, ;2009, 20(10): 1175-1178. doi: 10.1016/j.cclet.2009.05.019 shu

An efficient method for synthesis of organophosphorus compounds in aqueous media

Department of Chemistry, The University of Sistan and Baluchestan, P.O.Box 98135-674, Zahedan, Iran

Received Date: 20 February 2009

A convenient and facile one-pot synthesis of stable phosphorus ylides and 1,4-diionic organophosphorus compounds is reported by the reaction of triphenylphosphine, dialkylacetylenedicarboxylates and N-H, C-H or S-H acids in the presence of polyethyleneglycol (PEG), b-cyclodextrin (β-CD), glycerine (Gly) or ethyleneglycol (EG) in water.This methodology is of interest due to the use of water as a solvent, thus minimizing the cost operational hazards, and environmental pollution.
- Water,
- Triphenylphosphine,
- Acetylenic esters,
- Stable phosphorus ylides,
- Polyethyleneglycol,
- b-Cyclodextrin,
- Glycerine;Ethyleneglycol
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