Citation: Cai Hua Zhou, Li Jun Zhou, Long Tang, Yao Yu Wang. Formation of infinite 2D water layers in a crystal host[J]. Chinese Chemical Letters, ;2009, 20(7): 861-864. doi: 10.1016/j.cclet.2009.03.030 shu

Formation of infinite 2D water layers in a crystal host

a Department of Chemistry & Chemical Engineering, Yan'an University, Yan'an 716000, PR China;
b Department of Chemistry/Shaanxi Key Laboratory of Physico-inorganic Chemistry, Northwest University, Xi'an 710069, PR China;
c Department of Applied Chemistry, Xidian University, Xi'an 710071, PR China

Received Date: 22 September 2008

Fund Project: This work is supported by the Natural Science Foundation of Shaanxi Province (No.07JK439).

A self-assembled, (H₂O)₃₈ cluster stabilized by a mono-nuclear copper(Ⅱ) complex 1 namely {[Cu(phen)₂(CO₃)]·7H₂O} is characterized by X-ray diffraction studies. The adjacent (H₂O)₃₈ clusters connect together resulting in an infinite 2D water layer structure. The water morphology is stable at room temperature, but upon thermal decomposition, the water loss is irreversible.
- Water cluster,
- Supramolecular,
- Hydrogen-bonding
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