Citation: Ping Lian, Hai Yang Liu, Lan Ying Liu, Lei Shi, Huan Feng Jiang, Chi Kwong Chang. Synthesis of binaphthyl bridged chiral bis-corrole[J]. Chinese Chemical Letters, ;2009, 20(1): 21-24. doi: 10.1016/j.cclet.2008.10.016 shu

Synthesis of binaphthyl bridged chiral bis-corrole

a Department of Chemistry and Life Sicence, Gannan Normal University, Ganzhou 341000, China;
b Department of Chemistry, South China University of Technology, Guangzhou 510641, China;
c Department of Chemistry, The Hong Kong University of Science and Technology, Hong Kong, China

Received Date: 19 June 2008

Fund Project: This work was supported by Natural Science Foundation of China (Nos. 20771039 and 20572027), Research Grant Council of Hong Kong.

Chiral bis-corrole 1 and 2 were prepared by reaction of (s)-2,2'-bis(bromomethyl)-1,1'-binaphthyl and 10-(4-hydroxylphenyl)-5,15-bis(pentafluorophenyl)corrole or 10-(3-hydroxylphenyl)-5,15-bis(pentafluorophenyl)corrole in DMF at 60℃ in the presence of anhydrous K₂CO₃ with an isolated yield~8%. Both 1 and 2 exhibit unsymmetrical induced circular dichroism (ICD) in the soret band with positive exciton chirality.
- Chiral bis-corrole,
- Synthesis,
- ICD
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