Citation: Hai Fang Zhang, Zi Feng Li, Gang Li, Li Peng Wang, Jia Bin Li, Guang Jian Mei. Novel Zn(Ⅱ) ladder-like coordination polymer constructed from designed ferrocenyl ligand[J]. Chinese Chemical Letters, ;2008, 19(12): 1499-1503. doi: 10.1016/j.cclet.2008.09.056 shu

Novel Zn(Ⅱ) ladder-like coordination polymer constructed from designed ferrocenyl ligand

Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China

Received Date: 21 March 2008

Fund Project: We gratefully acknowledge the financial support by the National Natural Science Foundation of China (No. 20501017) and by the Key Project of Chinese Ministry of Education (No. 207067) and the Project Sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Chinese Ministry of Education and the Student Innovation Experimental Item of Zhengzhou University.

Reaction of Zn(NO₃)₂·6H₂O with 3-(4-carboxylphenylamino)-1-ferrocenyl-2-butylen-1-one (HL) and 4,4'-bipyridine (4,4'-bipy) in methanol solution resulted in a novel ladder-like coordination polymer {[Zn₂L₂(μ₂-L)₂(4,4'-bipy)₂]·MeOH}_n (1). Its crystal structure, thermal and electrochemical properties axe presented.
- Zinc(Ⅱ),
- Sturcture,
- Coordination polymer,
- Designed ferrocenyl figand,
- Thermal and electrochemical properties
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