Citation: Li Fei Zhi, Qiu Xiao Li, Yun Ling Li. A novel application of horseradish peroxidase: Oxidation of alcohol ethoxylate to alkylether carboxylic acid[J]. Chinese Chemical Letters, ;2008, 19(12): 1411-1414. doi: 10.1016/j.cclet.2008.09.030 shu

A novel application of horseradish peroxidase: Oxidation of alcohol ethoxylate to alkylether carboxylic acid

China Research Institute of Daily Chemical Industry, Taiyuan 030001, China

Received Date: 2 June 2008

Fund Project: We are grateful to the National Science and Technology Support Project of China (No. 2007BAE52B03) for the financial support.

A novel application of horseradish peroxidase (HRP) in the oxidation of alcohol ethoxylate to alkylether carboxylie acid in the present of H₂O₂ was reported in this paper. We propose the mechanism for the catalytic oxidation reaction is that the hydrogen transfers from the substrate to the ferryl oxygen to form the α-hydroxy carbon radical intermediate. The reaction offers a new approach for further research structure and catalytic mechanism of HRP and production of alkylether carboxylic acid.
- Horseradish peroxidase,
- Alcohol ethoxylate,
- Alkylether carboxylic acid
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