Citation: Er Jing Wang, Cheng Liang Wang, Qing Meng, Hong Xiang Li, Wen Ping Hu, Dao Ben Zhu. Syntheses of molecular wires containing redox center:Reversible redox property and good energy level matching with Au electrode[J]. Chinese Chemical Letters, ;2008, 19(11): 1285-1289. doi: 10.1016/j.cclet.2008.06.056 shu

Syntheses of molecular wires containing redox center:Reversible redox property and good energy level matching with Au electrode

a Beijing National Laboratory for Molecular Sciences and Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
b Graduate School of Chinese Academy of Sciences, Beijing 100039, China

Received Date: 6 May 2008

Fund Project: This work was supported by National Natural Sciences Foundation of China (Nos. 20402015,60771031).

Molecular wires with tetrathiafulvalene (TTF) as redox center were synthesized and characterized.UV-vis spectra and cyclic voltammetry showed these wires had good reversible redox behavior under ambient conditions and their HOMO energy levels (~-5.0 eV) matched well with the Fermi level of Au (~-5.1 eV).
- Charge transfer,
- Molecular wires,
- Redox center,
- Tctrathiafulvalene
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