Citation: Yi Feng Zhou, Jin Qi, Dan Ni Zhu, BoYang Yu. Two new steroidal glycosides from Ophiopogon japonicus[J]. Chinese Chemical Letters, ;2008, 19(9): 1086-1088. doi: 10.1016/j.cclet.2008.06.026 shu

Two new steroidal glycosides from Ophiopogon japonicus

Department of Complex Prescription of TCM, China Pharmaceutical University, Shennong Road, Nanjing 210038, China

Received Date: 31 January 2008

Fund Project: This research was financially supported by the grant (No. 30672603) and by the grant of the "111 Project" from the Ministry of Education of China and the State Administration of Foreign Expert Affairs of China (No. 111-2-07)

Two new C₂₇-steroidal glycosides were isolated from the fibrous roots of Ophiopogon japonicus. The spectral analysis and chemical evidence revealed their chemical structures to be (25R)-spirost-5,14-dien-3β-yl-O-α-L-rhanmopyranosyl-(1→2)-β-D-xylopyranosyl-(1→4)-β-D-glucopyranoside (1) and ophiogenin 3-O-β-D-glucopyranoside (2).
- Ophiopogon japonicus,
- Liliaceae,
- C₂₇-steroidal glycoside
1. [1]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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