Citation: Farhad Shirini, Saeideh Saeidi. Efficient oxidative deprotection of trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers under solvent-free conditions[J]. Chinese Chemical Letters, ;2008, 19(6): 676-680. doi: 10.1016/j.cclet.2008.04.005 shu

Efficient oxidative deprotection of trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers under solvent-free conditions

Department of Chemistry, College of Science, University of Guilan, Rasht 41335, Islamic Republic of Iran

Received Date: 8 January 2008

Fund Project: The authors acknowledge the financial supports from National Nature Science Foundation (Grant Nos. 20674071,20774078 and 20434020) and the Special Funds for Major State Basic Research Projects (No. 2005CB623802).

A mild, efficient and fast method for direct oxidation of trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers to their corresponding carbonyl compounds using trinitratocerium (IV) bromate (TNCB) supported on NaHSO₄·H₂O under solvent-flee conditions is reported.
- Oxidative deprotection,
- Trinitratocerium (IV) bromate,
- Trimethylsilyl ethers,
- Tetrahydropyranyl ethers,
- Methoxymethyl ethers
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