Citation: Wen Pei, Xiang Mei Wu. D301 resin as a solid base for phosphine-free Heck reactions with heteroaryl halides[J]. Chinese Chemical Letters, ;2008, 19(4): 399-402. doi: 10.1016/j.cclet.2008.01.034 shu

D301 resin as a solid base for phosphine-free Heck reactions with heteroaryl halides

Wen Pei ^a, ,
Xiang Mei Wu ^a,b

a College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310014, China;
b College of Chemistry and Life Science, Lishui University, Lishui 323000, China

Received Date: 29 October 2007

Fund Project: We are grateful to the financial support of the Natural Science Foundation of China (No. 20572100) and the open foundation of the key discipline of industrial catalysis of Zhejiang.

A new and practical method of the D301 resin, a weak basic anion exchange resin with secondary amine functionality (Grade Matrix Structure:Styrene-DVB D301R), used as base to Heck reactions catalyzed by palladium reagent without phosphine compound as ligand is described.It was found that the D301 resin used as base is an efficient and reusable base and can be regenerated and recycled in the reaction.The olefination of heteroaryl halides prepared the corresponding products in good yields using D301 resin as base.
- Heck reaction,
- Palladium,
- Phosphine-free catalysts,
- D301 resin
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