Citation: Xiao Ling Guo, Yun Yin Niu, Qing Li Wang, Ben Lai Wu, Hong Yun Zhang, Hong Wei Hou, Yi Han, Ling Fang Wang. Formation of a three-dimensional bispyridyl based metal–organic architecture containing unique Ag···Ag (d10–d10) interactions[J]. Chinese Chemical Letters, ;2008, 19(5): 604-606. doi: 10.1016/j.cclet.2008.01.020 shu

Formation of a three-dimensional bispyridyl based metal–organic architecture containing unique Ag···Ag (d10–d10) interactions

Department of Chemistry, Zhengzhou University, Henan 450052, China

Received Date: 10 October 2007

Fund Project: This research was funded by the Science Foundation for Distinguished Young Scholars of Henan Province (No. 0612002800) and the NSFC (No.20671083).

A novel co-ordination polymer based on IB metal thiocyanates, [Ag₂(NCS)₂(4,4'-bipy)]_n (1)(4,4'-bipy=4,4'-bispyridine), hasbeen synthesized by the pre-assembly method and characterized by X-ray crystallography. The complex exists as a three-dimensional network consisting of (AgSCN)_n undulating layers linked by 4,4'-bipy bridges.
- d¹⁰-d¹⁰ interaction,
- Metal thiocyanates,
- Crystal structure,
- Supramolecular structure,
- Molecular structure
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