Citation: Sheng Hua Li, Si Ping Pang, Xiao Tong Li, Yong Zhong Yu, Xin Qi Zhao. Synthesis of new tetrazene (N-N=N-N)-linked bi (1,2,4-triazole)[J]. Chinese Chemical Letters, ;2007, 18(10): 1176-1177. doi: 10.1016/j.cclet.2007.08.018 shu

Synthesis of new tetrazene (N-N=N-N)-linked bi (1,2,4-triazole)

a School of Material Science & Technology, Beijing Institute of Technology, Beijing 10081, China;
b School of Life Science & Technology, Beijing Institute of Technology, Beijing 100081, China

Received Date: 25 May 2007

Fund Project: We are grateful to the National Natural Science Foundation of China (No.10576007) for financial support for this work.

The reaction of 4-amino-1, 2, 4-triazole with sodium dichloroisocyanurate (SDCI) afforded new tetrazene(N-N=N-N)-linked bi(1, 2, 4-triazole) 2a in excellent yield. Increasing the molar ratio of SDCI to 4-amino-1, 2, 4-triazole, the chlorinated product 1, 5, 5'-trichloro-4, 4'-azo-1, 2, 4-triazole (2b) was formed. These new compounds have been characterized by MS, ¹H NMR, ¹³C NMR, and elemental analysis.
- Synthesis,
- Triazole,
- Tetrazene
1. [1]
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4. [4]
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