Citation: Fenglan Liang, Deyun Ma, Wuwan Xiong, Yanping Liu, Xin Yu, Xiaobing Wang, Fang Yang, Tong Liu, Yang Guo, Zaiwang Zhao, Shijie Li. 有机/无机5,10,15,20-四(4-磺基苯基)卟啉/Bi₂WO₆ S型异质结用于增强光催化降解水中抗生素[J]. Acta Physico-Chimica Sinica, ;2026, 42(11): 100384. doi: 10.1016/j.actphy.2026.100384 shu

有机/无机5,10,15,20-四(4-磺基苯基)卟啉/Bi₂WO₆ S型异质结用于增强光催化降解水中抗生素

Fenglan Liang ¹ ,
Deyun Ma ^1,, ,
Wuwan Xiong ¹ ,
Yanping Liu ^2,, ,
Xin Yu ^3,, ,
Xiaobing Wang ⁴ ,
Fang Yang ⁵ ,
Tong Liu ⁶ ,
Yang Guo ⁷ ,
Zaiwang Zhao ⁸ ,
Shijie Li ^2,3,,

1.
School of Life Sciences, School of Food and Pharmaceutical Engineering, School of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, Guangdong Province, China;
2.
Zhejiang Key Laboratory of Pollution Control for Port-Petrochemical Industry, National Engineering Research Center for Marine Aquaculture, Zhejiang Ocean University, Zhoushan 316022, Zhejiang Province, China;
3.
State Key Laboratory of Green Chemical Synthesis and Conversion, College of New Energy and Intelligent Manufacturing, Henan University, Zhengzhou 450046, Henan Province, China;
4.
School of Chemistry and Civil Engineering, Shaoguan University, Shaoguan 512005, Guangdong Province, China;
5.
College of Mechanical and Automotive Engineering, Shanghai University of Engineering Science, Shanghai 201620, China;
6.
Key Laboratory of Green Chemical Process, Ministry of Education, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, Hubei Province, China;
7.
State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control, Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210000, Jiangsu Province, China;
8.
College of Energy Materials and Chemistry, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010070, Inner Mongolia Autonomous Region, China

Corresponding author: Deyun Ma, Yanping Liu, Xin Yu, Shijie Li,
Received Date: 20 June 2026
Revised Date: 30 July 2026
Accepted Date: 6 August 2026

太阳能驱动催化反应提供了一条环境友好且能源可持续的途径，以应对紧迫的全球能源和环境挑战。然而，其实际应用仍受限于现有光催化剂性能不佳。在此，我们报道了一种新型有机/无机异质结光催化剂，即5,10,15,20-四(4-磺基苯基)卟啉(TPPS)/Bi₂WO₆ (BWO)，通过将TPPS锚定在BWO微球上制备而成。这种独特结构显著增强了异质界面处的内建电场(IEF)，从而促进两种组分之间高效的电荷载流子迁移。值得注意的是，具有强氧化能力的光生空穴积累在BWO表面，并参与羟基自由基(·OH)的生成。同时，分离在TPPS组分上的强还原性电子被分子氧迅速捕获，将其还原为超氧自由基(·O₂^-)。这种协同电荷分配加速了系统内最强还原性和氧化性物种的分离及功能化利用。所产生的活性自由基，连同表面积累的空穴，作为主要活性物种，驱动了90.2%的优异四环素降解效率。因此，TPPS/BWO异质结实现了四环素降解速率常数约为原始BWO的3.2倍。机理研究结合实验表征与密度泛函理论(DFT)计算揭示，高活性源于TPPS与BWO之间形成的有机/无机S型异质结。这种构型有效保留了异质结系统的优异氧化还原能力。总体而言，这项工作为光催化环境修复中有机/无机异质界面的合理设计提供了新见解。
- Organic/inorganic heterojunction,
- Bi₂WO₆,
- TPPS,
- Internal electric field,
- S-scheme mechanism,
- Water purification
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

有机/无机5,10,15,20-四(4-磺基苯基)卟啉/Bi2WO6 S型异质结用于增强光催化降解水中抗生素

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通讯作者: 陈斌, bchen63@163.com

有机/无机5,10,15,20-四(4-磺基苯基)卟啉/Bi₂WO₆ S型异质结用于增强光催化降解水中抗生素