Citation: Xuqiang Hao, Yuanjin He, Xue Wang, Yuqiang Hao, Zhiliang Jin. Co掺杂诱导S型CoCdS/石墨炔异质结不对称电荷分布及其宽光谱光催化析氢[J]. Acta Physico-Chimica Sinica, ;2026, 42(11): 100376. doi: 10.1016/j.actphy.2026.100376 shu

Co掺杂诱导S型CoCdS/石墨炔异质结不对称电荷分布及其宽光谱光催化析氢

Xuqiang Hao ^1,2,, ,
Yuanjin He ^1,2 ,
Xue Wang ^1,2 ,
Yuqiang Hao ^1,2 ,
Zhiliang Jin ^1,2

1.
School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, Ningxia Hui Autonomous Region, China;
2.
Ningxia Key Laboratory of Solar Chemical Conversion Technology, Key Laboratory for Chemical Engineering and Technology, State Ethnic Affairs Commission, North Minzu University, Yinchuan 750021, Ningxia Hui Autonomous Region, China

Corresponding author: Xuqiang Hao, haoxuqiang@nun.edu.cn
Received Date: 1 July 2026
Revised Date: 25 July 2026
Accepted Date: 26 July 2026

杂原子掺杂能够打破金属硫化物的本征电子对称性，是促进电荷分离的有效策略。本研究通过水热法合成了钴掺杂硫化镉(CoCdS)纳米颗粒，并将其与二维石墨炔(GDY)耦合构建GDY/CoCdS S型异质结，用于高效宽光谱光催化产氢。钴掺杂诱导CdS中局部不对称电荷分布，削弱S-H相互作用并降低氢脱附能垒，从而加速表面析氢反应。同时，钴掺杂还产生局部内建电场，显著增强CdS内部的本征电荷分离，并协同促进S型异质结中的界面电荷转移。原位X射线光电子能谱(XPS)分析与差分电荷密度计算证实了GDY/CoCdS异质界面的S型电荷转移机制，该机制极大加速了光生载流子的分离与迁移。此外，GDY凭借其宽光谱捕获能力和光热效应，赋予复合材料更宽的光响应范围并增强析氢反应动力学。因此，15%GDY/CoCdS在可见光照射下4 h内产氢量达4.8 mmol g^-1，分别是纯CoCdS和GDY的约9.6倍和48倍。本研究为通过钴掺杂诱导S型异质结中不对称电荷调控实现高效宽光谱光催化产氢提供了可行策略。
- S-scheme heterojunction,
- Photocatalytic hydrogen evolution,
- Graphdiyne,
- Photothermal effect,
- Asymmetric charge redistribution
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沈阳化工大学材料科学与工程学院沈阳 110142